A C-84 Selective Porphyrin Macrocycle with an Adaptable Cavity Constructed Through Alkyne Metathesis

Chenxi Zhang; Hai Long; Wei Zhang

doi:10.1039/c2cc32571c

A C-84 Selective Porphyrin Macrocycle with an Adaptable Cavity Constructed Through Alkyne Metathesis

Chenxi Zhang, Hai Long, Wei Zhang

Computational Science

University of Colorado Boulder

Research output: Contribution to journal › Article › peer-review

42 Scopus Citations

Abstract

A bisporphyrin macrocycle was constructed from a porphyrin-based diyne monomer in one step through alkyne metathesis. The fullerene binding studies (C₆₀, C₇₀ and C₈₄) showed the highest binding affinity of the macrocycle for C₈₄, which is in great contrast to its bisporphyrin four-armed cage analogue that showed the strongest binding with C₇₀.

Original language	American English
Pages (from-to)	6172-6174
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	49
DOIs	https://doi.org/10.1039/c2cc32571c https://doi.org/10.1039/c2cc32571c
State	Published - 23 May 2012

NREL Publication Number

NREL/JA-2C00-55817

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title = "A C-84 Selective Porphyrin Macrocycle with an Adaptable Cavity Constructed Through Alkyne Metathesis",

abstract = "A bisporphyrin macrocycle was constructed from a porphyrin-based diyne monomer in one step through alkyne metathesis. The fullerene binding studies (C60, C70 and C84) showed the highest binding affinity of the macrocycle for C84, which is in great contrast to its bisporphyrin four-armed cage analogue that showed the strongest binding with C70.",

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AU - Long, Hai

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AB - A bisporphyrin macrocycle was constructed from a porphyrin-based diyne monomer in one step through alkyne metathesis. The fullerene binding studies (C60, C70 and C84) showed the highest binding affinity of the macrocycle for C84, which is in great contrast to its bisporphyrin four-armed cage analogue that showed the strongest binding with C70.

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A C-84 Selective Porphyrin Macrocycle with an Adaptable Cavity Constructed Through Alkyne Metathesis

Abstract

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