Adaptive Pore Opening to Form Tailored Adsorption Sites in a Cooperatively Flexible Framework Enables Record Inverse Propane/Propylene Separation

Ryan Klein, Lukas Bingel, Arijit Halder, Marcus Carter, Benjamin Trump, Eric Bloch, Wei Zhou, Krista Walton, Craig Brown, C. McGuirk

Research output: Contribution to journalArticlepeer-review

5 Scopus Citations

Abstract

A proposed low-energy alternative to the separation of alkanes from alkenes by energy-intensive cryogenic distillation is separation by porous adsorbents. Unfortunately, most adsorbents preferentially take up the desired, high-value major component alkene, requiring frequent regeneration. Adsorbents with inverse selectivity for the minor component alkane would enable the direct production of purified, reagent-grade alkene, greatly reducing global energy consumption. However, such materials are exceedingly rare, especially for propane/propylene separation. Here, we report that through adaptive and spontaneous pore size and shape adaptation to optimize an ensemble of weak noncovalent interactions, the structurally responsive metal-organic framework CdIF-13 (sod-Cd(benzimidazolate)2) exhibits inverse selectivity for propane over propylene with record-setting separation performance under industrially relevant temperature, pressure, and mixture conditions. Powder synchrotron X-ray diffraction measurements combined with first-principles calculations yield atomic-scale insight and reveal the induced fit mechanism of adsorbate-specific pore adaptation and ensemble interactions between ligands and adsorbates. Dynamic column breakthrough measurements confirm that CdIF-13 displays selectivity under mixed-component conditions of varying ratios, with a record measured selectivity factor of ..alpha.. approximately 3 at 95:5 propylene:propane at 298 K and 1 bar. When sequenced with a low-cost rigid adsorbent, we demonstrated the direct purification of propylene under ambient conditions. This combined atomic-level structural characterization and performance testing firmly establishes how cooperatively flexible materials can be capable of unprecedented separation factors.
Original languageAmerican English
Pages (from-to)21955-21965
Number of pages11
JournalJournal of the American Chemical Society
Volume145
Issue number40
DOIs
StatePublished - 2023

NREL Publication Number

  • NREL/JA-5900-85399

Keywords

  • breakthrough
  • diffraction
  • isotherm
  • metal-organic framework
  • propane propylene separation
  • separations

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