Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework

Jacob Tarver, Tomce Runcevski, Matthew Kapelewski, Rodolfo Torres-Gavosto, Craig Brown, Jeffrey Long

Research output: Contribution to journalArticlepeer-review

45 Scopus Citations

Abstract

One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules--specifically hydrogen, methane, or carbon dioxide.
Original languageAmerican English
Pages (from-to)8251-8254
Number of pages4
JournalChemical Communications
Volume52
Issue number53
DOIs
StatePublished - 2016

NREL Publication Number

  • NREL/JA-5900-66698

Keywords

  • elemental analysis
  • gas adsorption
  • inelastic neutron scattering spectroscopy
  • infrared spectroscopy
  • Langmuir fitting
  • neutron powder diffraction
  • x-ray powder diffraction

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