Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework

Jacob Tarver; Tomce Runcevski; Matthew Kapelewski; Rodolfo Torres-Gavosto; Craig Brown; Jeffrey Long

doi:10.1039/C6CC02494G

Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework

Jacob Tarver, Tomce Runcevski, Matthew Kapelewski, Rodolfo Torres-Gavosto, Craig Brown, Jeffrey Long

Chemistry and Nanoscience

Research output: Contribution to journal › Article › peer-review

48 Scopus Citations

Abstract

One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules--specifically hydrogen, methane, or carbon dioxide.

Original language	American English
Pages (from-to)	8251-8254
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	53
DOIs	https://doi.org/10.1039/C6CC02494G
State	Published - 2016

NREL Publication Number

NREL/JA-5900-66698

Keywords

elemental analysis
gas adsorption
inelastic neutron scattering spectroscopy
infrared spectroscopy
Langmuir fitting
neutron powder diffraction
x-ray powder diffraction

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10.1039/C6CC02494G

Cite this

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title = "Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework",

abstract = "One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules--specifically hydrogen, methane, or carbon dioxide.",

keywords = "elemental analysis, gas adsorption, inelastic neutron scattering spectroscopy, infrared spectroscopy, Langmuir fitting, neutron powder diffraction, x-ray powder diffraction",

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T1 - Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework

AU - Tarver, Jacob

AU - Runcevski, Tomce

AU - Kapelewski, Matthew

AU - Torres-Gavosto, Rodolfo

AU - Brown, Craig

AU - Long, Jeffrey

PY - 2016

Y1 - 2016

N2 - One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules--specifically hydrogen, methane, or carbon dioxide.

AB - One strategy to markedly increase the gas storage capacity of metal-organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules--specifically hydrogen, methane, or carbon dioxide.

KW - elemental analysis

KW - gas adsorption

KW - inelastic neutron scattering spectroscopy

KW - infrared spectroscopy

KW - Langmuir fitting

KW - neutron powder diffraction

KW - x-ray powder diffraction

U2 - 10.1039/C6CC02494G

DO - 10.1039/C6CC02494G

M3 - Article

SN - 1359-7345

VL - 52

SP - 8251

EP - 8254

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

Adsorption of Two Gas Molecules at a Single Metal Site in a Metal-Organic Framework

Abstract

NREL Publication Number

Keywords

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