Analysis of Thermochemical Energy Storage in Metal Carbonates: Characterizing Cycling-Induced Degradation

Michael Adams; Tae Kim; Samuel Pennell; Judith Vidal; Akanksha Menon

doi:10.1039/D5CC04302F

Analysis of Thermochemical Energy Storage in Metal Carbonates: Characterizing Cycling-Induced Degradation

Michael Adams
, Tae Kim
, Samuel Pennell
, Judith Vidal
, Akanksha Menon

Building Technologies and Science Center

Research output: Contribution to journal › Article › peer-review

Abstract

A solid-gas reaction rate modeling framework is applied to characterize degradation in thermochemical materials induced by thermal cycling. Time constants and a kinetic conversion ratio are established for a representative carbonation-calcination reaction, which provides insight into degradation mechanisms and reveals a mitigation strategy by tuning reaction duration.

Original language	American English
Number of pages	5
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/D5CC04302F
State	Published - 2025

NLR Publication Number

NLR/JA-5500-95880

Keywords

degradation
thermal cycling
thermal energy storage
thermochemical materials

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10.1039/D5CC04302F

Cite this

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title = "Analysis of Thermochemical Energy Storage in Metal Carbonates: Characterizing Cycling-Induced Degradation",

abstract = "A solid-gas reaction rate modeling framework is applied to characterize degradation in thermochemical materials induced by thermal cycling. Time constants and a kinetic conversion ratio are established for a representative carbonation-calcination reaction, which provides insight into degradation mechanisms and reveals a mitigation strategy by tuning reaction duration.",

keywords = "degradation, thermal cycling, thermal energy storage, thermochemical materials",

author = "Michael Adams and Tae Kim and Samuel Pennell and Judith Vidal and Akanksha Menon",

year = "2025",

doi = "10.1039/D5CC04302F",

language = "American English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Analysis of Thermochemical Energy Storage in Metal Carbonates: Characterizing Cycling-Induced Degradation

AU - Adams, Michael

AU - Kim, Tae

AU - Pennell, Samuel

AU - Vidal, Judith

AU - Menon, Akanksha

PY - 2025

Y1 - 2025

N2 - A solid-gas reaction rate modeling framework is applied to characterize degradation in thermochemical materials induced by thermal cycling. Time constants and a kinetic conversion ratio are established for a representative carbonation-calcination reaction, which provides insight into degradation mechanisms and reveals a mitigation strategy by tuning reaction duration.

AB - A solid-gas reaction rate modeling framework is applied to characterize degradation in thermochemical materials induced by thermal cycling. Time constants and a kinetic conversion ratio are established for a representative carbonation-calcination reaction, which provides insight into degradation mechanisms and reveals a mitigation strategy by tuning reaction duration.

KW - degradation

KW - thermal cycling

KW - thermal energy storage

KW - thermochemical materials

U2 - 10.1039/D5CC04302F

DO - 10.1039/D5CC04302F

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Analysis of Thermochemical Energy Storage in Metal Carbonates: Characterizing Cycling-Induced Degradation

Abstract

NLR Publication Number

Keywords

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