Atomic Ordering-Induced Band Gap Reductions in GaAsSb Epilayers Grown by Molecular Beam Epitaxy

B. P. Gorman, A. G. Norman, R. Lukic-Zrnic, C. L. Littler, H. R. Moutinho, T. D. Golding, A. G. Birdwell

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Abstract

A series of Ga As1-x Sbx epilayers (0.51<x<0.71) grown by molecular-beam epitaxy on GaAs substrates with surface orientations of (001), (001) -8° toward (111) A, (001) -8° toward (111) B, (115) A, (115) B, (113) A, and (113) B were investigated using temperature-dependent Fourier transform infrared (FTIR) spectroscopy and transmission electron microscopy. Atomic ordering in these epilayers was observed from a decrease in the energy gap measured by FTIR absorption and corroborated by superlattice reflections in electron diffraction. Contrary to previous investigations of ordering in III-V alloys, a marked energy-gap reduction, corresponding to CuPt- B -type ordering, is observed in the Ga As1-x Sbx grown on (111) A -type substrate offcuts.

Original languageAmerican English
Article number063701
Number of pages7
JournalJournal of Applied Physics
Volume97
Issue number6
DOIs
StatePublished - 2005

NREL Publication Number

  • NREL/JA-520-38383

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