Abstract
An electrolyzer capable of converting CO2 into carbon-based fuels and chemicals will need to operate at current densities in excess of 200 mA cm-2 for industrial applications. This chapter provides a comprehensive review of design considerations for electrolytic flow cell reactors capable of operation at these high current densities. We highlight how the dynamic chemical environment at these conditions is differentiated from experimental conditions more common to academic investigations, and provide a survey of reactor architectures that are being investigated for mediating the CO2 reduction reaction.
Original language | American English |
---|---|
Title of host publication | Carbon Dioxide Electrochemistry: Homogeneous and Heterogeneous Catalysis |
Subtitle of host publication | Energy and Environment Series No. 28 |
Editors | Marc Robert, Cyrille Costentin, Kim Daasbjerg |
Publisher | Royal Society of Chemistry |
Pages | 408-432 |
Number of pages | 25 |
Edition | 28 |
ISBN (Electronic) | 9781788015462 |
DOIs | |
State | Published - 2021 |
Publication series
Name | RSC Energy and Environment Series |
---|---|
Number | 28 |
Volume | 2021-January |
ISSN (Print) | 2044-0774 |
ISSN (Electronic) | 2044-0782 |
Bibliographical note
Publisher Copyright:© 2021 The Royal Society of Chemistry.
NREL Publication Number
- NREL/CH-5900-78582
Keywords
- carbon-based fuels
- chemical environment
- CO2 reduction
- design considerations
- electrochemical reactor
- experimental conditions
- flow cell reactors
- high current densities