Abstract
This work describes investigations of CIS solar cells with ZnO buffer layers. Studies are concentrating on determining optimum ZnO buffer layer properties that will yield the maximum ZnO/CIS solar cell efficiency. Buffer layers are grown by chemical vapor deposition (CVD) by reacting a zinc adduct with tetrahydrofuran to grow ZnO. Substrate temperatures (T/sub sub/) have been varied from 100 deg.C to 350 deg. C, with the best device performance obtained for T/sub sub/ .apprx. 225 deg C to 250 deg C. These studies were conducted with substrates obtained from Siemens Solar (CIGSS) and NREL (CIGS). ZnO/CIS solar cells were fabricated by first depositing a ZnO buffer layer, followed by deposition of a low resistivity ZnO top contact layer and a Al/Ag collector grid. Several cells have beenfabricated with an area of 0.44 cm/sup 2/ that have total area efficiencies greater than 11%. In particular, a cell was fabricated with a Siemens substrate that exhibited a total area efficiency of 11.3%, and one based on a NREL substrate that has a total area efficiency of 12%. This work has focused on determining optimum deposition parameters for CVD ZnO buffer layers. It is clear that inorder to achieve efficient ZnO/CIS cells, the buffer layer must be deposited with a high resisitivity.
Original language | American English |
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Pages | 997-1000 |
Number of pages | 4 |
DOIs | |
State | Published - 1996 |
Event | Twenty Fifth IEEE Photovoltaic Specialists Conference - Washington, D.C. Duration: 13 May 1996 → 17 May 1996 |
Conference
Conference | Twenty Fifth IEEE Photovoltaic Specialists Conference |
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City | Washington, D.C. |
Period | 13/05/96 → 17/05/96 |
Bibliographical note
Work performed by Washington State University, Richland, WashingtonNREL Publication Number
- NREL/CP-22436