Abstract
In this contribution, we present a comparative study of the luminescence of the kesterites Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) and their related chalcopyrite Cu(In,Ga)Se2 (CIGSe). Luminescence spectroscopy suggests that the electronic properties of Zn-rich, Cu-poor kesterites (both CZTS and CZTSe) and Cu-poor CIGSe are dictated by fluctuations of the electrostatic and chemical potentials. Thelarge redshift in the luminescence of grain boundaries in CIGSe, associated with the formation of a neutral barrier is clearly observed in CZTSe, and, to some extent, in CZTS. Kesterites can therefore replicate the fundamental electronic properties of CIGSe.
Original language | American English |
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Number of pages | 7 |
State | Published - 2012 |
Event | 2012 IEEE Photovoltaic Specialists Conference - Austin, Texas Duration: 3 Jun 2012 → 8 Jun 2012 |
Conference
Conference | 2012 IEEE Photovoltaic Specialists Conference |
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City | Austin, Texas |
Period | 3/06/12 → 8/06/12 |
NREL Publication Number
- NREL/CP-5200-54140
Keywords
- cathodoluminescence (CL) spectroscopy
- chalcopyrites
- kesterite
- thin films