Control of Doping in Cu2SnS3 Through Defects and Alloying

Lauryn L. Baranowski, Pawel Zawadzki, Steven Christensen, Dennis Nordlund, Stephan Lany, Adele C. Tamboli, Lynn Gedvilas, David S. Ginley, William Tumas, Eric S. Toberer, Andriy Zakutayev

Research output: Contribution to journalArticlepeer-review

133 Scopus Citations


As the world's demand for energy grows, the search for cost competitive and earth abundant thin film photovoltaic absorbers is becoming increasingly important. A promising approach to tackle this challenge is through thin film photovoltaics made of elements that are abundant in the Earth's crust. In this work, we focus on Cu2SnS3, a promising earth abundant absorber material. Recent publications have presented 3% and 6% device efficiencies using Cu2SnS3-based absorber materials and alloys, respectively. However, little is understood about the fundamental defect and doping physics of this material, which is needed for further improvements in device performance. Here, we identify the origins of the changes in doping in sputtered cubic Cu2SnS3 thin films using combinatorial experiments and first-principles theory. Experimentally, we find that the cubic Cu2SnS3 has a large phase width and that the electrical conductivity increases with increasing Cu and S content in the films, which cannot be fully explained by the theoretical point defect model. Instead, theoretical calcuations suggest that under Cu-rich conditions alloying with an isostructural metallic Cu3SnS4 phase occurs, causing high levels of p-type doping; this theory is consistent with experimental Raman and NEXAFS spectroscopy data. These experimental and theoretical works lead to the conclusion that Cu2SnS3 films must be grown both S-poor and Cu-poor in order to achieve moderate hole concentrations. These new insights enable the design of growth processes that target the desired carrier concentrations for solar cell fabrication. Using the strategies described above, we have been able to tune the carrier concentration over >3 orders of magnitude and achieve films with p-type doping of 1018 cm-3, facilitating future device integration of these films.

Original languageAmerican English
Pages (from-to)4951-4959
Number of pages9
JournalChemistry of Materials
Issue number17
StatePublished - 2014

Bibliographical note

Publisher Copyright:
© 2014 American Chemical Society.

NREL Publication Number

  • NREL/JA-5K00-62134


Dive into the research topics of 'Control of Doping in Cu2SnS3 Through Defects and Alloying'. Together they form a unique fingerprint.

Cite this