Covalently Bound Nitroxyl Radicals in an Organic Framework

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Abstract

A series of covalent organic framework (COF) structures is synthesized that possesses a tunable density of covalently bound nitroxyl radicals within the COF pores. The highest density of organic radicals produces an electron paramagnetic resonance (EPR) signal that suggests the majority of radicals strongly interact with other radicals, whereas for smaller loadings the EPR signals indicate the radicals are primarily isolated but with restricted motion. The dielectric loss as determined from microwave absorption of the framework structures compared with an amorphous control suggests that free motion of the radicals is inhibited when more than 25% of available sites are occupied. The ability to tune the mode of radical interactions and the subsequent effect on redox, electrical, and optical characteristics in a porous framework may lead to a class of structures with properties ideal for photoelectrochemistry or energy storage.

Original languageAmerican English
Pages (from-to)3660-3665
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume7
Issue number18
DOIs
StatePublished - 15 Sep 2016

Bibliographical note

Publisher Copyright:
© 2016 American Chemical Society.

NREL Publication Number

  • NREL/JA-5900-67035

Keywords

  • conductivity
  • covalent organic framework
  • organic radical

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