Cyclopropanation of Unsaturated Sugars with Ethyl Diazoacetate

doi:10.1016/0040-4039(96)00335-8

Cyclopropanation of Unsaturated Sugars with Ethyl Diazoacetate

NREL

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Abstract

The cyclopropanation of unsaturated sugars with ethyl diazoacetate and a metal catalyst provides ester-substituted 1,2-C-methylene carbohydrates in good to excellent yields. Ring opening of the cyclopropane has also been achieved providing C-2 branched glycosyl bromides.

Original language	American English
Pages (from-to)	2533-2536
Number of pages	4
Journal	Tetrahedron Letters
Volume	37
Issue number	15
DOIs	https://doi.org/10.1016/0040-4039(96)00335-8
State	Published - 1996

NLR Publication Number

NREL/JA-431-20453

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10.1016/0040-4039(96)00335-8

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@article{8d48be3f9a634d7183a8d36c27e12afb,

title = "Cyclopropanation of Unsaturated Sugars with Ethyl Diazoacetate",

abstract = "The cyclopropanation of unsaturated sugars with ethyl diazoacetate and a metal catalyst provides ester-substituted 1,2-C-methylene carbohydrates in good to excellent yields. Ring opening of the cyclopropane has also been achieved providing C-2 branched glycosyl bromides.",

author = "NREL",

year = "1996",

doi = "10.1016/0040-4039(96)00335-8",

language = "American English",

volume = "37",

pages = "2533--2536",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd.",

number = "15",

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T1 - Cyclopropanation of Unsaturated Sugars with Ethyl Diazoacetate

AU - NREL, null

PY - 1996

Y1 - 1996

N2 - The cyclopropanation of unsaturated sugars with ethyl diazoacetate and a metal catalyst provides ester-substituted 1,2-C-methylene carbohydrates in good to excellent yields. Ring opening of the cyclopropane has also been achieved providing C-2 branched glycosyl bromides.

AB - The cyclopropanation of unsaturated sugars with ethyl diazoacetate and a metal catalyst provides ester-substituted 1,2-C-methylene carbohydrates in good to excellent yields. Ring opening of the cyclopropane has also been achieved providing C-2 branched glycosyl bromides.

U2 - 10.1016/0040-4039(96)00335-8

DO - 10.1016/0040-4039(96)00335-8

M3 - Article

SN - 0040-4039

VL - 37

SP - 2533

EP - 2536

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 15

ER -

Cyclopropanation of Unsaturated Sugars with Ethyl Diazoacetate

Abstract

NLR Publication Number

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