Deactivation and Stability of K-CoMoSx Mixed Alcohol Synthesis Catalysts

Jesse E. Hensley, Svitlana Pylypenko, Daniel A. Ruddy

Research output: Contribution to journalArticlepeer-review

32 Scopus Citations

Abstract

Potassium-promoted cobalt molybdenum sulfide (K-CoMoSx) mixed alcohol synthesis catalysts were operated from 118 to 3969 h for the purpose of studying catalyst deactivation. Continuous and discontinuous sulfiding with H2S and methyl sulfides was considered. Fresh and discharged catalysts were analyzed via X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). When continuously sulfided, selectivity was maintained for thousands of hours. Without sulfur cofeed, catalysts exhibited a change in selectivity from alcohols to hydrocarbons over periods of hundreds of hours. Sulfur deprivation resulted in oxidization, carburization, and coking of the catalyst surface and segregation of cobalt into crystalline Co9S 8. It is suggested that in the absence of a sulfiding agent, the catalyst surface becomes more acidic (oxidized) promoting dehydration of alcohols (selectivity change) and coking (blocking active sites). Reintroduction of H2S may reverse oxidation on non-coked surfaces. Proper sulfur maintenance may render catalysts operable for years without need of regeneration or replacement.

Original languageAmerican English
Pages (from-to)199-208
Number of pages10
JournalJournal of Catalysis
Volume309
DOIs
StatePublished - 2014

NREL Publication Number

  • NREL/JA-5100-60542

Keywords

  • Carbides
  • Cobalt molybdenum sulfide
  • Coke
  • Deactivation
  • Mixed alcohols
  • Oxidation
  • Principal component analysis
  • Stability
  • XPS
  • XRD

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