Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?

Omar K. Farha; Christopher E. Wilmer; Ibrahim Eryazici; Brad G. Hauser; Philip A. Parilla; Kevin ONeill; Amy A. Sarjeant; Sonbinh T. Nguyen; Randall Q. Snurr; Joseph T. Hupp

doi:10.1021/ja302623w

Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?

Omar K. Farha, Christopher E. Wilmer, Ibrahim Eryazici, Brad G. Hauser, Philip A. Parilla, Kevin ONeill, Amy A. Sarjeant, Sonbinh T. Nguyen, Randall Q. Snurr, Joseph T. Hupp

Northwestern University

Research output: Contribution to journal › Article › peer-review

203 Scopus Citations

Abstract

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.

Original language	American English
Pages (from-to)	9860-9863
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	24
DOIs	https://doi.org/10.1021/ja302623w https://doi.org/10.1021/ja302623w
State	Published - 20 Jun 2012

NREL Publication Number

NREL/JA-5200-55919

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Cite this

Farha, O. K., Wilmer, C. E., Eryazici, I., Hauser, B. G., Parilla, P. A., ONeill, K., Sarjeant, A. A., Nguyen, S. T., Snurr, R. Q., & Hupp, J. T. (2012). Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls? Journal of the American Chemical Society, 134(24), 9860-9863. https://doi.org/10.1021/ja302623w, https://doi.org/10.1021/ja302623w

@article{1321f5ee93bd4d70bd08f9af7a0f0742,

title = "Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better than Phenyls?",

abstract = "We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.",

author = "Farha, {Omar K.} and Wilmer, {Christopher E.} and Ibrahim Eryazici and Hauser, {Brad G.} and Parilla, {Philip A.} and Kevin ONeill and Sarjeant, {Amy A.} and Nguyen, {Sonbinh T.} and Snurr, {Randall Q.} and Hupp, {Joseph T.}",

year = "2012",

month = jun,

day = "20",

doi = "10.1021/ja302623w",

language = "American English",

volume = "134",

pages = "9860--9863",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",