Direct Analysis of the Current Density vs. Voltage Curves of a CdTe Module During Outdoor Exposure

Dirk Jordan, Sarah Kurtz, Carolin Ulbrich, Andreas Gerber, Uwe Rau

Research output: Contribution to journalArticlepeer-review

7 Scopus Citations

Abstract

Current density-voltage (JV) curves of a CdTe photovoltaic module measured during 2.5years of outdoor operation are analyzed using a phenomenological four-parameter equation. This approach is shown to be more accurate than fitting the same data set to the conventional five parameter diode equation. The four extracted parameters are the short-circuit current density Jsc, open-circuit voltage Voc, and the differential resistances Rsc and Roc, i.e., the reciprocal slopes of the JV curves at short circuit and open circuit, respectively. The dependencies of all four parameters on module temperature and irradiation intensities are analyzed in terms of physically motivated models. The coefficients derived from these models are then used to transform the photovoltaic parameters to reference conditions and to investigate the degradation of the module. The models for Rsc and Roc involve voltage-dependent carrier collection. This feature appears prominent already in the initial JV curves, but becomes even more dominant with increasing exposure time. Voltage-dependent carrier collection also explains that the diode ideality factor determined from Voc vs. Jsc curves is different from that determined using Roc vs. 1/Jsc plots. The degradation of the module is essentially reflected in fill factor losses caused by a decrease of Rsc and an increase of Roc. Additionally, the Voc vs. log(Jsc) curves of the module behavior at low irradiation unveil an increasing influence of a double-exponential diode behavior.

Original languageAmerican English
Pages (from-to)88-100
Number of pages13
JournalSolar Energy
Volume113
DOIs
StatePublished - 2015

Bibliographical note

Publisher Copyright:
© 2014 Elsevier Ltd.

NREL Publication Number

  • NREL/JA-5J00-62090

Keywords

  • CdTe
  • Current-voltage characteristic
  • Degradation
  • Diode ideality factor
  • Monitoring
  • Reliability

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