Direct Imaging of Surface-Enhanced Raman Scattering in the Near Field

Peng Zhang; Steve Smith; Garry Rumbles; Michael E. Himmel

doi:10.1021/la048037a

Direct Imaging of Surface-Enhanced Raman Scattering in the Near Field

Peng Zhang, Steve Smith, Garry Rumbles, Michael E. Himmel

Research output: Contribution to journal › Article › peer-review

30 Scopus Citations

Abstract

By using near-field scanning microscopy/spectroscopy, we show that surface-enhanced Raman scattering (SERS) of rhodamine 6G deposited on self-affine silver colloidal film is localized to small, down to less than 200 nm, portions of the film. The locus of the SERS signals ("hot spots") does not necessarily reside in special topographic elements such as interstices and between nanoparticles. The local SERS enhancement is estimated to be over 3 orders of magnitude higher compared to the far-field measurements. Near-field imaging of SERS directly validates the theory of the optical response of self-affine fractal objects.

Original language	American English
Pages (from-to)	520-523
Number of pages	4
Journal	Langmuir
Volume	21
Issue number	2
DOIs	https://doi.org/10.1021/la048037a https://doi.org/10.1021/la048037a
State	Published - 2005

NREL Publication Number

NREL/JA-590-37894

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abstract = "By using near-field scanning microscopy/spectroscopy, we show that surface-enhanced Raman scattering (SERS) of rhodamine 6G deposited on self-affine silver colloidal film is localized to small, down to less than 200 nm, portions of the film. The locus of the SERS signals ({"}hot spots{"}) does not necessarily reside in special topographic elements such as interstices and between nanoparticles. The local SERS enhancement is estimated to be over 3 orders of magnitude higher compared to the far-field measurements. Near-field imaging of SERS directly validates the theory of the optical response of self-affine fractal objects.",

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AU - Rumbles, Garry

AU - Himmel, Michael E.

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AB - By using near-field scanning microscopy/spectroscopy, we show that surface-enhanced Raman scattering (SERS) of rhodamine 6G deposited on self-affine silver colloidal film is localized to small, down to less than 200 nm, portions of the film. The locus of the SERS signals ("hot spots") does not necessarily reside in special topographic elements such as interstices and between nanoparticles. The local SERS enhancement is estimated to be over 3 orders of magnitude higher compared to the far-field measurements. Near-field imaging of SERS directly validates the theory of the optical response of self-affine fractal objects.

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JO - Langmuir

JF - Langmuir

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ER -

Direct Imaging of Surface-Enhanced Raman Scattering in the Near Field

Abstract

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