Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

David Alie; Lynn Gedvilas; Zhiwei Wang; Robert Tenent; Chaiwat Engtrakul; Yanfa Yan; Sean E. Shaheen; Anne C. Dillon; Chunmei Ban

doi:10.1016/j.jssc.2013.10.023

Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

David Alie, Lynn Gedvilas, Zhiwei Wang, Robert Tenent, Chaiwat Engtrakul, Yanfa Yan, Sean E. Shaheen, Anne C. Dillon, Chunmei Ban

Research output: Contribution to journal › Article › peer-review

67 Scopus Citations

Abstract

Thermochromic VO₂ was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO₂ powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO₂ structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO₂ and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).

Original language	American English
Pages (from-to)	237-241
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	212
DOIs	https://doi.org/10.1016/j.jssc.2013.10.023 https://doi.org/10.1016/j.jssc.2013.10.023
State	Published - 2014

NREL Publication Number

NREL/JA-5900-60740

Keywords

Crystal phase
Thermochromic
Vanadium dioxide
VO (M)

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title = "Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction",

abstract = "Thermochromic VO2 was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO2 powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO2 structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO2 and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).",

keywords = "Crystal phase, Thermochromic, Vanadium dioxide, VO (M)",

author = "David Alie and Lynn Gedvilas and Zhiwei Wang and Robert Tenent and Chaiwat Engtrakul and Yanfa Yan and Shaheen, {Sean E.} and Dillon, {Anne C.} and Chunmei Ban",

year = "2014",

doi = "10.1016/j.jssc.2013.10.023",

language = "American English",

volume = "212",

pages = "237--241",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

AU - Alie, David

AU - Gedvilas, Lynn

AU - Wang, Zhiwei

AU - Tenent, Robert

AU - Engtrakul, Chaiwat

AU - Yan, Yanfa

AU - Shaheen, Sean E.

AU - Dillon, Anne C.

AU - Ban, Chunmei

PY - 2014

Y1 - 2014

N2 - Thermochromic VO2 was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO2 powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO2 structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO2 and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).

AB - Thermochromic VO2 was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO2 powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO2 structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO2 and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).

KW - Crystal phase

KW - Thermochromic

KW - Vanadium dioxide

KW - VO (M)

UR - http://www.scopus.com/inward/record.url?scp=84900673136&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2013.10.023

DO - 10.1016/j.jssc.2013.10.023

M3 - Article

AN - SCOPUS:84900673136

SN - 0022-4596

VL - 212

SP - 237

EP - 241

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

Abstract

NREL Publication Number

Keywords

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