Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

David Alie; Lynn Gedvilas; Zhiwei Wang; Robert Tenent; Chaiwat Engtrakul; Yanfa Yan; Sean E. Shaheen; Anne C. Dillon; Chunmei Ban

doi:10.1016/j.jssc.2013.10.023

Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

David Alie
, Lynn Gedvilas
, Zhiwei Wang
, Robert Tenent
, Chaiwat Engtrakul
, Yanfa Yan
, Sean E. Shaheen
, Anne C. Dillon
, Chunmei Ban

Research output: Contribution to journal › Article › peer-review

74 Scopus Citations

Abstract

Thermochromic VO₂ was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO₂ powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO₂ structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO₂ and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).

Original language	American English
Pages (from-to)	237-241
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	212
DOIs	https://doi.org/10.1016/j.jssc.2013.10.023 https://doi.org/10.1016/j.jssc.2013.10.023
State	Published - 2014

NLR Publication Number

NREL/JA-5900-60740

Keywords

Crystal phase
Thermochromic
Vanadium dioxide
VO (M)

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title = "Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction",

abstract = "Thermochromic VO2 was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO2 powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO2 structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO2 and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).",

keywords = "Crystal phase, Thermochromic, Vanadium dioxide, VO (M)",

author = "David Alie and Lynn Gedvilas and Zhiwei Wang and Robert Tenent and Chaiwat Engtrakul and Yanfa Yan and Shaheen, \{Sean E.\} and Dillon, \{Anne C.\} and Chunmei Ban",

year = "2014",

doi = "10.1016/j.jssc.2013.10.023",

language = "American English",

volume = "212",

pages = "237--241",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

AU - Alie, David

AU - Gedvilas, Lynn

AU - Wang, Zhiwei

AU - Tenent, Robert

AU - Engtrakul, Chaiwat

AU - Yan, Yanfa

AU - Shaheen, Sean E.

AU - Dillon, Anne C.

AU - Ban, Chunmei

PY - 2014

Y1 - 2014

N2 - Thermochromic VO2 was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO2 powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO2 structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO2 and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).

AB - Thermochromic VO2 was directly synthesized using hydrothermal techniques. The effects of formation conditions on the structure and morphology of the final product were studied through X-ray diffraction (XRD), and scanning electron microscopy (SEM). Unique hollow sphere morphology was observed for the synthesized VO2 powders. Ex-situ XRD studies after heat treatment confirmed the thermal stability of the VO2 structure. Thermochromic properties, as a consequence of the reversible structural transformation between monoclinic VO2 and tetragonal phases, were observed by Fourier transform infrared spectroscopy (FTIR).

KW - Crystal phase

KW - Thermochromic

KW - Vanadium dioxide

KW - VO (M)

UR - https://www.scopus.com/pages/publications/84900673136

U2 - 10.1016/j.jssc.2013.10.023

DO - 10.1016/j.jssc.2013.10.023

M3 - Article

AN - SCOPUS:84900673136

SN - 0022-4596

VL - 212

SP - 237

EP - 241

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Direct Synthesis of Thermochromic VO2 through Hydrothermal Reaction

Abstract

NLR Publication Number

Keywords

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