Dissolution of Oxygen Precipitate Nuclei in n-Type CZ-Si Wafers to Improve Their Material Quality: Experimental Results

Teh Tan, Ajay Upadhyaya, Keith Tate, Ajeet Rohatgi, Han Xu

    Research output: Contribution to journalArticlepeer-review

    13 Scopus Citations

    Abstract

    We present experimental results which show that oxygen-related precipitate nuclei (OPN) present in p-doped, n-type, Czochralski wafers can be dissolved using a flash-annealing process, yielding very high quality wafers for high-efficiency solar cells. Flash annealing consists of heating a wafer in an optical furnace to temperature between 1150 and 1250 degrees C for a short time. This process produces a large increase in the minority carrier lifetime (MCLT) and homogenizes each wafer. We have tested wafers from different axial locations of two ingots. All wafers reach nearly the same high value of MCLT. The OPN dissolution is confirmed by oxygen analysis using Fourier transform infrared spectra and injection-level dependence of MCLT.
    Original languageAmerican English
    Pages (from-to)97-103
    Number of pages7
    JournalIEEE Journal of Photovoltaics
    Volume7
    Issue number1
    DOIs
    StatePublished - 2017

    NREL Publication Number

    • NREL/JA-5J00-66519

    Keywords

    • charge carrier lifetime
    • chemical etching
    • optical furnace
    • silicon solar cells
    • spatial diversity

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