Effect of Sb on the Properties of GaInP Top Cells

Research output: Contribution to conferencePaperpeer-review

25 Scopus Citations

Abstract

It is well known that the efficiency of GaInP/GaAs tandem solar cells is limited by the band gap of the GaInP top cell, which, in turn, is determined by the degree of compositional ordering in the GaInP base layer. Attempts to raise the band gap by the addition of Al to the top cell have met with limited success due to the strong affinity between Al and oxygen. Here we investigate a different approach. It has been shown that the presence of antimony on the surface of GaInP during its growth suppresses the ordering process and increases the band gap. In this paper, we study the effects of Sb on the properties of GaInP top cells. We show that, in addition to raising the band gap of GaInP, it also increases the incorporation of Zn and changes the relative incorporation of Ga and In. These effects depend strongly on the substrate orientation, growth temperature and rate, and the Sb/P ratio in the gas phase. We show that the band gap of the GaInP top cell (and the Voc) can be increased without reducing the minority carrier collection efficiency. The implications of these results are presented and discussed.

Original languageAmerican English
Pages787-790
Number of pages4
DOIs
StatePublished - 2007
Event2006 IEEE 4th World Conference on Photovoltaic Energy Conversion, WCPEC-4 - Waikoloa, HI, United States
Duration: 7 May 200612 May 2006

Conference

Conference2006 IEEE 4th World Conference on Photovoltaic Energy Conversion, WCPEC-4
Country/TerritoryUnited States
CityWaikoloa, HI
Period7/05/0612/05/06

Bibliographical note

For preprint version see NREL/CP-520-39903

NREL Publication Number

  • NREL/CP-520-41291

Fingerprint

Dive into the research topics of 'Effect of Sb on the Properties of GaInP Top Cells'. Together they form a unique fingerprint.

Cite this