Effect of ZnO Processing on the Photovoltage of ZnO/Poly(3-hexylthiophene) Solar Cells

Dana C. Olson; Yun Ju Lee; Matthew S. White; Nikos Kopidakis; Sean E. Shaheen; David S. Ginley; James A. Voigt; Julia W.P. Hsu

doi:10.1021/jp802626u

Effect of ZnO Processing on the Photovoltage of ZnO/Poly(3-hexylthiophene) Solar Cells

Dana C. Olson, Yun Ju Lee, Matthew S. White, Nikos Kopidakis, Sean E. Shaheen, David S. Ginley, James A. Voigt, Julia W.P. Hsu

Research output: Contribution to journal › Article › peer-review

122 Scopus Citations

Abstract

Proper contact and band alignment across the heterojunction interface is critical to the performance of hybrid pi-conjugated polymer-nanostructured metal oxide photovoltaic devices. We investigated the effect of ZnO surface processing on ZnO/poly(3-hexylthiolphene) device performance. Devices in which the ZnO films/ nanorods were heated at 150°C in air exhibited an open circuit voltage ~200 mV higher than devices with ZnO treated by UV/ozone. We conclude that the differences observed in the two types of devices predominantly arise from changes in interfacial dipoles, and intermediate materials processing can be critical to solar cell performance.

Original language	American English
Pages (from-to)	9544-9547
Number of pages	4
Journal	Journal of Physical Chemistry C
Volume	112
Issue number	26
DOIs	https://doi.org/10.1021/jp802626u https://doi.org/10.1021/jp802626u
State	Published - 2008

NREL Publication Number

NREL/JA-520-44081

Keywords

materials science
solar cells

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title = "Effect of ZnO Processing on the Photovoltage of ZnO/Poly(3-hexylthiophene) Solar Cells",

abstract = "Proper contact and band alignment across the heterojunction interface is critical to the performance of hybrid pi-conjugated polymer-nanostructured metal oxide photovoltaic devices. We investigated the effect of ZnO surface processing on ZnO/poly(3-hexylthiolphene) device performance. Devices in which the ZnO films/ nanorods were heated at 150°C in air exhibited an open circuit voltage \textasciitilde{}200 mV higher than devices with ZnO treated by UV/ozone. We conclude that the differences observed in the two types of devices predominantly arise from changes in interfacial dipoles, and intermediate materials processing can be critical to solar cell performance.",

keywords = "materials science, solar cells",

author = "Olson, \{Dana C.\} and Lee, \{Yun Ju\} and White, \{Matthew S.\} and Nikos Kopidakis and Shaheen, \{Sean E.\} and Ginley, \{David S.\} and Voigt, \{James A.\} and Hsu, \{Julia W.P.\}",

year = "2008",

doi = "10.1021/jp802626u",

language = "American English",

volume = "112",

pages = "9544--9547",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

publisher = "American Chemical Society",

number = "26",

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TY - JOUR

T1 - Effect of ZnO Processing on the Photovoltage of ZnO/Poly(3-hexylthiophene) Solar Cells

AU - Olson, Dana C.

AU - Lee, Yun Ju

AU - White, Matthew S.

AU - Kopidakis, Nikos

AU - Shaheen, Sean E.

AU - Ginley, David S.

AU - Voigt, James A.

AU - Hsu, Julia W.P.

PY - 2008

Y1 - 2008

N2 - Proper contact and band alignment across the heterojunction interface is critical to the performance of hybrid pi-conjugated polymer-nanostructured metal oxide photovoltaic devices. We investigated the effect of ZnO surface processing on ZnO/poly(3-hexylthiolphene) device performance. Devices in which the ZnO films/ nanorods were heated at 150°C in air exhibited an open circuit voltage ~200 mV higher than devices with ZnO treated by UV/ozone. We conclude that the differences observed in the two types of devices predominantly arise from changes in interfacial dipoles, and intermediate materials processing can be critical to solar cell performance.

AB - Proper contact and band alignment across the heterojunction interface is critical to the performance of hybrid pi-conjugated polymer-nanostructured metal oxide photovoltaic devices. We investigated the effect of ZnO surface processing on ZnO/poly(3-hexylthiolphene) device performance. Devices in which the ZnO films/ nanorods were heated at 150°C in air exhibited an open circuit voltage ~200 mV higher than devices with ZnO treated by UV/ozone. We conclude that the differences observed in the two types of devices predominantly arise from changes in interfacial dipoles, and intermediate materials processing can be critical to solar cell performance.

KW - materials science

KW - solar cells

UR - https://www.scopus.com/pages/publications/48249095620

U2 - 10.1021/jp802626u

DO - 10.1021/jp802626u

M3 - Article

AN - SCOPUS:48249095620

SN - 1932-7447

VL - 112

SP - 9544

EP - 9547

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 26

ER -

Effect of ZnO Processing on the Photovoltage of ZnO/Poly(3-hexylthiophene) Solar Cells

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Keywords

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