Efficient Organic Excitonic Solar Cells with Carbon Nanotubes Replacing In2O3:Sn as the Transparent Electrode

Jao Van De Lagemaat, Teresa Barnes, Garry Rumbles, Timothy J. Courts, Sean E. Shaheen, Chris Weeks, Paul Glatkowski, Igor Levitsky, Jorma Peltola

Research output: Contribution to conferencePaperpeer-review

Abstract

We report two organic excitonic solar cell structures with the conventional ITO anode replaced by a thin single-walled carbon nanotube (SWCNT) layer. The first structure, SWCNT/PED0T/P3HT:PCBM/AI, gave a nonoptimized device efficiency of 2.61%, which is competitive with ITO-based devices. The second, SWCNT/P3HT:PCBM/AI, is unique, as it did not use PEDOT as a hole selective contact. This had a promising efficiency of 1.43%. The open structure of the SWCNT network, and its inherent compatibility with the chlorobenzene solvent used to deposit the P3HT:PCBM, allow for intimate intermixing with the active layers of the device and the elimination of PEDOT. The strong rectifying behavior of the device shows that nanotubes are selective for holes and are not recombination sites in the active layer of the device. This excitonic solar cell is the first measurably efficient organic device produced without ITO and PEDOT.

Original languageAmerican English
Pages183-185
Number of pages3
DOIs
StatePublished - 2006
Event2006 IEEE 4th World Conference on Photovoltaic Energy Conversion, WCPEC-4 - Waikoloa, HI, United States
Duration: 7 May 200612 May 2006

Conference

Conference2006 IEEE 4th World Conference on Photovoltaic Energy Conversion, WCPEC-4
Country/TerritoryUnited States
CityWaikoloa, HI
Period7/05/0612/05/06

NREL Publication Number

  • NREL/CP-590-39848

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