Electrical Activity of Intragrain Defects in Polycrystalline Silicon Layers Obtained by Aluminum-Induced Crystallization and Epitaxy

D. Van Gestel, M. J. Romero, I. Gordon, L. Carnel, J. D'Haen, G. Beaucarne, M. Al-Jassim, J. Poortmans

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Abstract

Defect etching revealed a very large density (∼ 109 cm-2) of intragrain defects in polycrystalline silicon (pc-Si) layers obtained through aluminum-induced crystallization of amorphous Si and epitaxy. Electron-beam-induced current measurements showed a strong recombination activity at these defects. Cathodoluminescence measurements showed the presence of two deep-level radiative transitions (0.85 and 0.93 eV) with a relative intensity varying from grain to grain. These results indicate that the unexpected quasi-independence on the grain size of the open-circuit voltage of these pc-Si solar cells is due to the presence of numerous electrically active intragrain defects.

Original languageAmerican English
Article numberArticle No. 092103
Number of pages3
JournalApplied Physics Letters
Volume90
Issue number9
DOIs
StatePublished - 2007

NREL Publication Number

  • NREL/JA-520-41685

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