Enhanced Catalyst Durability and Sulfur Tolerance by Atomic Layer Deposition: Cooperative Research and Development Final Report, CRADA Number CRD-18-00727

This CRADA advanced the use of atomic layer deposition (ALD) catalyst coatings to improve sulfur tolerance and demonstrate improved catalyst durability for biomass conversion chemistries. This project leveraged National Laboratory and industry expertise for ALD catalyst coating development between NREL, ALD NanoSolutions, Inc. ("ALD NanoSolutions"), and Johnson Matthey PLC ("Johnson Matthey"). To better understand the role of ALD coatings on catalyst activity and durability, a joint experimental and computational effort combined bench-scale ALD catalyst synthesis, material characterization, catalyst testing, and modeling of catalyst surface energetics. In addition, to demonstrate the commercial relevance of this technology, scaled ALD coated catalysts were subjected to continuous testing and accelerated aging to validate performance gains. Results were used to inform ALD catalyst coating manufacturing cost models, as well as biobased chemical process cost models.