Evaluating the Performance and Reliability of Screen-Printable Fire-Through Copper Paste on PERC Solar Cells

Research output: NLRPresentation

Abstract

A bifacial silicon heterojunction solar cell demands approximately 210 mg usage of silver paste (9 busbars, 24.5%, bifacial, M6 size wafer). Copper is an excellent alternative to silver: 100x cheaper, similar elecvtrical resistivities, and 1000x more abundant. Successful demonstration of large area selective emitter PERC solar cells using Cu fire-through paste with FF approximately 75% and approximately 19%. Paste chemistry results in oxide-based Cu diffusion barrier, leading to good reliability of the devices: 1000h DHT giving a 3.5% efficiency drop. The additional series resistance still needs to be lowered. Printed and fired cell performance is governed mostly by pFF, especially J02 ; same for DHT degradation. Further improvement in printing and firing optimization for lower series resistance and higher FF.
Original languageAmerican English
Number of pages19
StatePublished - 2024

Publication series

NamePresented at the 14th International Conference on Silicon Photovoltaics, 15-19 April 2024, Chambery, France

NLR Publication Number

  • NREL/PR-5900-90444

Keywords

  • Ag
  • copper
  • Cu
  • EDS
  • energy-dispersive x-ray spectroscopy
  • fire-through
  • PERC
  • photovoltaic
  • PV
  • screen-printable
  • silver
  • solar cell

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