Far Infrared Properties of Bulk Sintered and Thin Film Zn2SnO4

M. V. Nikolić; T. Ivetić; D. L. Young; K. M. Paraskevopoulos; T. T. Zorba; V. Blagojević; P. M. Nikolić; D. Vasiljević-Radović; M. M. Ristić

doi:10.1016/j.mseb.2006.12.005

Far Infrared Properties of Bulk Sintered and Thin Film Zn2SnO4

M. V. Nikolić, T. Ivetić, D. L. Young, K. M. Paraskevopoulos, T. T. Zorba, V. Blagojević, P. M. Nikolić, D. Vasiljević-Radović, M. M. Ristić

Chemistry and Nanoscience

Research output: Contribution to journal › Article › peer-review

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Abstract

Room temperature far infrared reflectivity spectra of single phase spinel zinc-stannate thin films, prepared by rf magnetron sputtering on a glass substrate, and bulk sintered samples were measured. The sintered samples were obtained by mechanical activation of starting ZnO and SnO₂ powders for 10 min followed by sintering at 1300 °C for 2 h. The reflectivity diagrams obtained for bulk samples were numerically analyzed using the four-parameter model of coupled oscillators. The optical parameters were determined for six observed ionic oscillators belonging to the spinel structure and two additional oscillators originating from the sintering procedure resulting from pores and grain boundaries. The reflectivity diagrams obtained for thin film samples were analyzed using the four-parameter model for optical phonons with a standard optical multi-layer technique.

Original language	American English
Pages (from-to)	7-11
Number of pages	5
Journal	Materials Science and Engineering: B
Volume	138
Issue number	1
DOIs	https://doi.org/10.1016/j.mseb.2006.12.005 https://doi.org/10.1016/j.mseb.2006.12.005
State	Published - 2007

NREL Publication Number

NREL/JA-520-41772

Keywords

Infrared spectroscopy
Optical properties
Thin films
Zinc-stannate

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@article{c456dbf1454247dfafa9bfe50403aeba,

title = "Far Infrared Properties of Bulk Sintered and Thin Film Zn2SnO4",

abstract = "Room temperature far infrared reflectivity spectra of single phase spinel zinc-stannate thin films, prepared by rf magnetron sputtering on a glass substrate, and bulk sintered samples were measured. The sintered samples were obtained by mechanical activation of starting ZnO and SnO2 powders for 10 min followed by sintering at 1300 °C for 2 h. The reflectivity diagrams obtained for bulk samples were numerically analyzed using the four-parameter model of coupled oscillators. The optical parameters were determined for six observed ionic oscillators belonging to the spinel structure and two additional oscillators originating from the sintering procedure resulting from pores and grain boundaries. The reflectivity diagrams obtained for thin film samples were analyzed using the four-parameter model for optical phonons with a standard optical multi-layer technique.",

keywords = "Infrared spectroscopy, Optical properties, Thin films, Zinc-stannate",

author = "Nikoli{\'c}, {M. V.} and T. Iveti{\'c} and Young, {D. L.} and Paraskevopoulos, {K. M.} and Zorba, {T. T.} and V. Blagojevi{\'c} and Nikoli{\'c}, {P. M.} and D. Vasiljevi{\'c}-Radovi{\'c} and Risti{\'c}, {M. M.}",

year = "2007",

doi = "10.1016/j.mseb.2006.12.005",

language = "American English",

volume = "138",

pages = "7--11",

journal = "Materials Science and Engineering: B",

issn = "0921-5107",

publisher = "Elsevier Ltd.",

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TY - JOUR

T1 - Far Infrared Properties of Bulk Sintered and Thin Film Zn2SnO4

AU - Nikolić, M. V.

AU - Ivetić, T.

AU - Young, D. L.

AU - Paraskevopoulos, K. M.

AU - Zorba, T. T.

AU - Blagojević, V.

AU - Nikolić, P. M.

AU - Vasiljević-Radović, D.

AU - Ristić, M. M.

PY - 2007

Y1 - 2007

N2 - Room temperature far infrared reflectivity spectra of single phase spinel zinc-stannate thin films, prepared by rf magnetron sputtering on a glass substrate, and bulk sintered samples were measured. The sintered samples were obtained by mechanical activation of starting ZnO and SnO2 powders for 10 min followed by sintering at 1300 °C for 2 h. The reflectivity diagrams obtained for bulk samples were numerically analyzed using the four-parameter model of coupled oscillators. The optical parameters were determined for six observed ionic oscillators belonging to the spinel structure and two additional oscillators originating from the sintering procedure resulting from pores and grain boundaries. The reflectivity diagrams obtained for thin film samples were analyzed using the four-parameter model for optical phonons with a standard optical multi-layer technique.

AB - Room temperature far infrared reflectivity spectra of single phase spinel zinc-stannate thin films, prepared by rf magnetron sputtering on a glass substrate, and bulk sintered samples were measured. The sintered samples were obtained by mechanical activation of starting ZnO and SnO2 powders for 10 min followed by sintering at 1300 °C for 2 h. The reflectivity diagrams obtained for bulk samples were numerically analyzed using the four-parameter model of coupled oscillators. The optical parameters were determined for six observed ionic oscillators belonging to the spinel structure and two additional oscillators originating from the sintering procedure resulting from pores and grain boundaries. The reflectivity diagrams obtained for thin film samples were analyzed using the four-parameter model for optical phonons with a standard optical multi-layer technique.

KW - Infrared spectroscopy

KW - Optical properties

KW - Thin films

KW - Zinc-stannate

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U2 - 10.1016/j.mseb.2006.12.005

DO - 10.1016/j.mseb.2006.12.005

M3 - Article

AN - SCOPUS:33847301632

SN - 0921-5107

VL - 138

SP - 7

EP - 11

JO - Materials Science and Engineering: B

JF - Materials Science and Engineering: B

IS - 1

ER -

Far Infrared Properties of Bulk Sintered and Thin Film Zn2SnO4

Abstract

NREL Publication Number

Keywords

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