Abstract
III-V semiconductors grown on silicon substrates are very attractive for lower-cost, high-efficiency multijunction solar cells, but lattice-mismatched alloys that result in high dislocation densities have been unable to achieve satisfactory performance. GaNxP1-x-yASy is a direct-gap III-V alloy that can be grown lattice-matched to Si when y = 4.7 × - 0.1. We propose the use of lattice-matched GaNPAs on silicon for high-efficiency multijunction solar cells. We have grown GaNxP1-x-yAsy on GaP (with a similar lattice constant to silicon) by metal-organic chemical vapor phase epitaxy with direct band-gaps in the range of 1.5 to 2.0 eV. We demonstrate the performance of single-junction GaNxP1-x-yAsy solar cells grown on GaP substrates and discuss the prospects for the development of monolithic high-efficiency multijunction solar cells based on silicon substrates.
| Original language | American English |
|---|---|
| Pages | 864-867 |
| Number of pages | 4 |
| State | Published - 2002 |
| Event | 29th IEEE Photovoltaic Specialists Conference - New Orleans, LA, United States Duration: 19 May 2002 → 24 May 2002 |
Conference
| Conference | 29th IEEE Photovoltaic Specialists Conference |
|---|---|
| Country/Territory | United States |
| City | New Orleans, LA |
| Period | 19/05/02 → 24/05/02 |
Bibliographical note
For preprint version including full text online document, see NREL/CP-520-32200NLR Publication Number
- NREL/CP-520-33723
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