In-Situ Studies of the Growth of Amorphous and Microcrystalline Silicon Using Real-Time Spectroscopic Ellipsometry

    Research output: Contribution to conferencePaper

    Abstract

    Real-time, in-situ characterization of hot-wire chemical vapor deposition (HWCVD) growth of hydrogenated silicon (Si:H) thin films offers unique insight into the properties of the materials and mechanisms of their growth. We have used in-situ spectroscopic ellipsometry to characterize Si:H crystallinity as a function of film thickness and deposition conditions. We find that the transition fromamorphous to microcrystalline growth is a strong function of film thickness and hydrogen dilution, and a weak function of substrate temperature. We have expressed this information in terms of a color-coded phase-space map of the amorphous to microcrystalline transition in HWCVD growth on crystalline Si substrates.
    Original languageAmerican English
    Number of pages7
    StatePublished - 2003
    EventNational Center for Photovoltaics (NCPV) and Solar Program Review Meeting - Denver, Colorado
    Duration: 24 Mar 200326 Mar 2003

    Conference

    ConferenceNational Center for Photovoltaics (NCPV) and Solar Program Review Meeting
    CityDenver, Colorado
    Period24/03/0326/03/03

    NREL Publication Number

    • NREL/CP-520-33571

    Keywords

    • characterizations
    • crystallinity
    • hot-wire chemical vapor deposition (HWCVD)
    • hydrogenated amorphous silicon (a-Si:H)
    • real-time spectroscopic ellipsometry (RTSE)

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