Influence of Metallic Contaminants on the Electrochemical and Thermal Behavior of Li-Ion Electrodes

Kae Fink, Bryant Polzin, John Vaughey, Joshua Major, Alison Dunlop, Stephen Trask, Gerald Jeka, Jeffrey Spangenberger, Matthew Keyser

Research output: Contribution to journalArticlepeer-review

12 Scopus Citations

Abstract

Emerging nondestructive (direct) recycling techniques for lithium-ion batteries may introduce metallic impurities into recycled electrodes. In the present work, the impact of such nonionic contaminants on the practical performance of both anode and cathode materials is evaluated using a synergistic combination of electrochemical and thermal analysis. The impurities under study have been selected through evaluation of industrially shredded batteries, and include Fe0, Al0, Mg0, Cu0, and Si0. The electrochemical behavior of materials containing each individual contaminant at either the anode or the cathode is evaluated in both half-cell and full-cell format. Further, the first-cycle thermal signatures of full cells are used to validate and complement electrochemical signatures, and the two techniques are used in conjunction to suggest distinct mechanisms of electrochemical reactivity for the various impurities. At the anode, metallic contaminants are found to disrupt performance through direct reaction with Li and may serve as weak catalysts to accelerate electrolyte degradation. At the cathode, metallic contaminants show evidence of crossover during formation cycling to disrupt SEI formation. We suggest that coupled electrochemical and thermal analysis may be used to both identify the presence of contaminants and to elucidate specific mechanisms of reactivity for metallic impurities under anodic and cathodic conditions.

Original languageAmerican English
Article numberArticle No. 230760
Number of pages11
JournalJournal of Power Sources
Volume518
DOIs
StatePublished - 15 Jan 2022

Bibliographical note

Publisher Copyright:
© 2021 Elsevier B.V.

NREL Publication Number

  • NREL/JA-5700-80522

Keywords

  • Contaminant
  • Differential electrochemical analysis
  • Direct recycling
  • Isothermal microcalorimetry
  • Lithium-ion battery recycling

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