Interfacial Crystallization and Electronic Properties of Platinum Double Salts

Kenji Honda; Kazuyuki Chiba; Eishun Tsuchida; Arthur J. Frank

doi:10.1007/BF01168965

Interfacial Crystallization and Electronic Properties of Platinum Double Salts

Kenji Honda, Kazuyuki Chiba, Eishun Tsuchida, Arthur J. Frank

Chemistry and Nanoscience

Research output: Contribution to journal › Article › peer-review

15 Scopus Citations

Abstract

Insoluble platinum double salts were crystallized by a novel method involving a solid-liquid interface. The platinum complexes included Magnus Green Salt, MGS ([Pt(NH)₃)₄]²⁺ [PtCl₄]^2-) and PBC ([Pt(bpy)₂]²⁺[Pt(CN)₄]^2-). The crystallization and molecular ordering of MGS and PBC on a Nafion membrane were achieved by controlling the diffusion of the cation and anion components to the solid-liquid interface. The electrical conductivity of the MGS film on Nafion was greatly augmented by oxidizing the polynuclear complex. A device consisting of the PBC film on Nafion, methyl viologen, and triethanolamine displayed photoelectrochromism.

Original language	American English
Pages (from-to)	4004-4008
Number of pages	5
Journal	Journal of Materials Science
Volume	24
Issue number	11
DOIs	https://doi.org/10.1007/BF01168965 https://doi.org/10.1007/BF01168965
State	Published - 1989

NREL Publication Number

ACNR/JA-233-10953

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title = "Interfacial Crystallization and Electronic Properties of Platinum Double Salts",

abstract = "Insoluble platinum double salts were crystallized by a novel method involving a solid-liquid interface. The platinum complexes included Magnus Green Salt, MGS ([Pt(NH)3)4]2+ [PtCl4]2-) and PBC ([Pt(bpy)2]2+[Pt(CN)4]2-). The crystallization and molecular ordering of MGS and PBC on a Nafion membrane were achieved by controlling the diffusion of the cation and anion components to the solid-liquid interface. The electrical conductivity of the MGS film on Nafion was greatly augmented by oxidizing the polynuclear complex. A device consisting of the PBC film on Nafion, methyl viologen, and triethanolamine displayed photoelectrochromism.",

author = "Kenji Honda and Kazuyuki Chiba and Eishun Tsuchida and Frank, {Arthur J.}",

year = "1989",

doi = "10.1007/BF01168965",

language = "American English",

volume = "24",

pages = "4004--4008",

journal = "Journal of Materials Science",

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T1 - Interfacial Crystallization and Electronic Properties of Platinum Double Salts

AU - Honda, Kenji

AU - Chiba, Kazuyuki

AU - Tsuchida, Eishun

AU - Frank, Arthur J.

PY - 1989

Y1 - 1989

N2 - Insoluble platinum double salts were crystallized by a novel method involving a solid-liquid interface. The platinum complexes included Magnus Green Salt, MGS ([Pt(NH)3)4]2+ [PtCl4]2-) and PBC ([Pt(bpy)2]2+[Pt(CN)4]2-). The crystallization and molecular ordering of MGS and PBC on a Nafion membrane were achieved by controlling the diffusion of the cation and anion components to the solid-liquid interface. The electrical conductivity of the MGS film on Nafion was greatly augmented by oxidizing the polynuclear complex. A device consisting of the PBC film on Nafion, methyl viologen, and triethanolamine displayed photoelectrochromism.

AB - Insoluble platinum double salts were crystallized by a novel method involving a solid-liquid interface. The platinum complexes included Magnus Green Salt, MGS ([Pt(NH)3)4]2+ [PtCl4]2-) and PBC ([Pt(bpy)2]2+[Pt(CN)4]2-). The crystallization and molecular ordering of MGS and PBC on a Nafion membrane were achieved by controlling the diffusion of the cation and anion components to the solid-liquid interface. The electrical conductivity of the MGS film on Nafion was greatly augmented by oxidizing the polynuclear complex. A device consisting of the PBC film on Nafion, methyl viologen, and triethanolamine displayed photoelectrochromism.

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DO - 10.1007/BF01168965

M3 - Article

AN - SCOPUS:0024770784

SN - 0022-2461

VL - 24

SP - 4004

EP - 4008

JO - Journal of Materials Science

JF - Journal of Materials Science

IS - 11

ER -

Interfacial Crystallization and Electronic Properties of Platinum Double Salts

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