Interplay Between Strain and Thickness on the Effective Carrier Lifetime of Buffer-Mediated Epitaxial Germanium Probed by the Photoconductance Decay Technique

Shuvodip Bhattacharya, Steven Johnston, Suman Datta, Mantu Hudait

Research output: Contribution to journalArticlepeer-review

2 Scopus Citations

Abstract

We report contactless effective minority carrier lifetime of epitaxially grown unstrained and in-plane <110> biaxially tensile-strained (001) germanium (..epsilon..-Ge) epilayers measured using microwave-reflectance photoconductance decay measurements. Strained Ge epilayers were grown using InxGa1-xAs linearly graded buffers on (001) GaAs substrates. Using homogeneous excitation of unstrained Ge epilayers, thickness-dependent separation of minority carrier lifetime components under low injection conditions yielded a bulk lifetime of 114 +/- 2 ns and low surface recombination velocity of 21.3 +/- 0.04 cm/s. More notably, an effective minority carrier lifetime of >100 ns obtained from sub-50 nm 1.6% tensile-strained Ge epilayers showed no degradation relative to the unstrained counterpart. Detailed material characterization using X-ray diffractometry revealed successful strain transfer of 0.61 and 0.89% to the Ge epilayers via InxGa1-xAs metamorphic buffers and confirms pseudomorphic growth. Lattice coherence observed at the e-Ge epilayer and InxGa1-xAs buffer heterointerfaces via transmission electron microscopy substantiates the prime material quality achieved. The relatively high carrier lifetimes achieved are an indicator of excellent material quality and provide a path forward to realize low-threshold Ge laser sources.
Original languageAmerican English
Pages (from-to)3190-3197
Number of pages8
JournalACS Applied Electronic Materials
Volume5
Issue number6
DOIs
StatePublished - 2023

NREL Publication Number

  • NREL/JA-5K00-85206

Keywords

  • bulk lifetime
  • carrier lifetime
  • germanium
  • molecular beam epitaxy
  • photoconductance
  • surface recombination velocity
  • tensile strain
  • x-ray diffraction

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