Intrinsic Chemical Reactivity of Solid-Electrolyte Interphase Components in Silicon-Lithium Alloy Anode Batteries Probed by FTIR Spectroscopy

Ryan Pekarek, Alec Affolter, Lauryn Baranowski, Jaclyn Coyle, Tingzheng Hou, Eric Sivonxay, Brenda Smith, Rebecca McAuliffe, Kristin Persson, Baris Key, Christopher Apblett, Gabriel Veith, Nathan Neale

Research output: Contribution to journalArticlepeer-review

52 Scopus Citations

Abstract

In this work we report the solid reaction products from the chemical reaction of aprotic battery electrolyte and three purported components of the Si-based anode SEI : SiO2 nanoparticles (NPs), lithium silicate (LixSiOy) powders, and Si NPs. We use FTIR and classical molecular dynamics/density functional perturbation theory to assess the solid products remaining with these model materials after exposure to electrolyte. The absence of electrochemical bias provides a view of the chemical speciation resulting from early-stage chemical reactivity during battery assembly as well as under open circuit storage conditions. We believe these species represent the initial stages of SEI growth and predict they likely drive subsequent chemical and electrochemical reactions by controlling molecular interactons at the Si active material interface. We find that nominally equivalent materials react differently even before any electrochemistry is performed (e.g., acidic SiO2 dissolves whereas alkaline SiO2 is relatively robust), and derive new understanding of the chemical species that could and could not form stable SEI components in Si-based anodes. These results can be used to inform how to passivate Si anode surfaces and potentially generate an artificially engineered SEI that would be stable and enable next-generation battery anodes.

Original languageAmerican English
Pages (from-to)7897-7906
Number of pages10
JournalJournal of Materials Chemistry A
Volume8
Issue number16
DOIs
StatePublished - 28 Apr 2020

Bibliographical note

Publisher Copyright:
© 2020 The Royal Society of Chemistry.

NREL Publication Number

  • NREL/JA-5900-75298

Keywords

  • electrochemical
  • Li-ion
  • silicon

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