Inverted Bulk-Heterojunction Organic Photovoltaic Device Using a Solution-Derived ZnO Underlayer

M. S. White, D. C. Olson, S. E. Shaheen, N. Kopidakis, D. S. Ginley

Research output: Contribution to journalArticlepeer-review

800 Scopus Citations

Abstract

Inverted organic photovoltaic devices based on a blend of poly(3-hexylthiophene) and a fullerene have been developed by inserting a solution-processed ZnO interlayer between the indium tin oxide (ITO) electrode and the active layer using Ag as a hole-collecting back contact. Efficient electron extraction through the ZnO and hole extraction through the Ag, with minimal loss in open-circuit potential, is observed with a certified power conversion efficiency of 2.58%. The inverted architecture removes the need for the use of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) as an ITO modifier and for the use of a low-work-function metal as the back contact in the device.

Original languageAmerican English
Article number143517
Number of pages3
JournalApplied Physics Letters
Volume89
Issue number14
DOIs
StatePublished - 2006

NREL Publication Number

  • NREL/JA-520-39645

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