Abstract
Recent computational studies have predicted many new ternary nitrides, revealing synthetic opportunities in this underexplored phase space. However, synthesizing new ternary nitrides is difficult, in part because intermediate and product phases often have high cohesive energies that inhibit diffusion. Here, we report the synthesis of two new phases, calcium zirconium nitride (CaZrN2) and calcium hafnium nitride (CaHfN2), by solid state metathesis reactions between Ca3N2 and MCl4 (M = Zr, Hf).
Original language | American English |
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Pages (from-to) | 4001-4012 |
Number of pages | 12 |
Journal | Journal of the American Chemical Society |
Volume | 146 |
Issue number | 6 |
DOIs | |
State | Published - 2024 |
NREL Publication Number
- NREL/JA-5K00-87938
Keywords
- inorganic
- nitride
- semiconductor
- solid
- synthesis