Metal Phosphide Catalysts and Methods for Making the Same and Uses Thereof

Susan Habas; Daniel Ruddy; Frederick Baddour; Joshua Schaidle; Jun Wang

Metal Phosphide Catalysts and Methods for Making the Same and Uses Thereof

Susan Habas (Inventor), Daniel Ruddy (Inventor), Frederick Baddour (Inventor), Joshua Schaidle (Inventor), Jun Wang (Inventor)

Catalytic Carbon Transformation and Scale-Up Center

National Renewable Energy Laboratory

Research output: Patent

Abstract

The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.

Original language	American English
Patent number	9,636,664
Filing date	2/05/17
State	Published - 2017

NREL Publication Number

NREL/PT-5100-69099

Keywords

nanoparticles
precursors

Access to Document

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Cite this

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title = "Metal Phosphide Catalysts and Methods for Making the Same and Uses Thereof",

abstract = "The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.",

keywords = "nanoparticles, precursors",

author = "Susan Habas and Daniel Ruddy and Frederick Baddour and Joshua Schaidle and Jun Wang",

year = "2017",

language = "American English",

type = "Patent",

note = "9,636,664",

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TY - PAT

T1 - Metal Phosphide Catalysts and Methods for Making the Same and Uses Thereof

AU - Habas, Susan

AU - Ruddy, Daniel

AU - Baddour, Frederick

AU - Schaidle, Joshua

AU - Wang, Jun

PY - 2017

Y1 - 2017

N2 - The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.

AB - The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.

KW - nanoparticles

KW - precursors

M3 - Patent

M1 - 9,636,664

Y2 - 2017/05/02

ER -

Metal Phosphide Catalysts and Methods for Making the Same and Uses Thereof

Abstract

NREL Publication Number

Keywords

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