Moisture Transport in Silica Gel Particle Beds - I. Theoretical Study

Diffusion mechanisms of moisture within silica gel particles are investigated. It is found that for microporous silica gel surface diffusion is the dominant mechanism of moisture transport, while for macroporous silica gel both Knudsen and surface diffusions are important. A model is proposed for simultaneous heat and mass transfer in a thin packed bed of desiccant particles, which accounts for diffusion of moisture into the particles by both Knudsen and surface diffusions. Using finite difference methods to solve the resulting partial differential equations, predictions are made for the response of thin beds of silica gel particles to a step change in air inlet conditions, and compared to a pseudo-gas-side controlled model commonly used for the design of desiccant dehumidifiers for solar desiccant cooling applications.