Multivariate Zeolitic Imidazolate Frameworks with an Inverting Trend in Flexibility

Arijit Halder, Ryan Klein, Rachel Lively, C. McGuirk

Research output: Contribution to journalArticlepeer-review

5 Scopus Citations

Abstract

Through systematic linker substitution in a flexible zeolitic imidazolate framework (ZIF) with step-shaped adsorption-desorption, structural intermediates between the known open and closed phases were isolated. Reflecting this, modulative sorption behaviour with an inverting adsorption pressure trend—in which the step pressure decreases and then increases again with increasing mixed linker concentration—is observed, highlighting how linker substitution modifies the energetic landscape of framework flexibility.

Original languageAmerican English
Pages (from-to)11394-11397
Number of pages4
JournalChemical Communications
Volume58
Issue number81
DOIs
StatePublished - 22 Sep 2022

Bibliographical note

Publisher Copyright:
© 2022 The Royal Society of Chemistry.

NREL Publication Number

  • NREL/JA-5900-83664

Keywords

  • flexible framework
  • gas storage
  • MOF

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