n-Cu-In-Chalcogenide-Based Photoelectrochemical Cells

David Cahen; G. Dagen; G. Hodes; Y. Mirovsky; Y. W. Chen; J. C.W. Folmer; P. J. Ireland; R. Noufi; J. A. Turner; K. J. Bachmann; S. Endo; C. Rincon; G. A. Sawatzky; M. Tomkiewicz

doi:10.1016/0146-3535(84)90043-1

n-Cu-In-Chalcogenide-Based Photoelectrochemical Cells

David Cahen
, G. Dagen
, G. Hodes
, Y. Mirovsky
, Y. W. Chen
, J. C.W. Folmer
, P. J. Ireland
, R. Noufi
, J. A. Turner
, K. J. Bachmann
, S. Endo
, C. Rincon
, G. A. Sawatzky
, M. Tomkiewicz

Chemistry and Nanoscience

Research output: Contribution to conference › Paper › peer-review

6 Scopus Citations

Abstract

n-CuInSe₂, n-CuInS₂ and n-CuIn₅S₈ were used as photoanodes in electrochemical photovoltaic solar cells, using aqueous polysulfide electrolyte. CuIn₅S₈ was found to be less stable than CuInS₂. Because of kinetic limitations of polysulfide-based systems, the CuInSe₂/aqueous polyiodide cell was studied and optimized to yield stable, near 12% AM1 conversion efficiency. The strategy used to achieve this is described. (Photo)electrochemical methods were used to characterize the semiconductor materials and a photoelectrochemical test was developed to gauge the photovoltaic activity of p-CuInSe₂ layers used in solid state cells. Solid-state chemical studies on the (Cu₂X)²-(In₂X₃)(X=S,Se) system, and the use of photoelectrochemistry in them, are briefly described.

Original language	American English
Pages	263-270
Number of pages	8
DOIs	https://doi.org/10.1016/0146-3535(84)90043-1
State	Published - 1984
Event	Sixth International Conference on Ternary and Multinary Compounds - Caracas, Venezuela Duration: 15 Aug 1984 → 17 Aug 1984

Conference

Conference	Sixth International Conference on Ternary and Multinary Compounds
City	Caracas, Venezuela
Period	15/08/84 → 17/08/84

Bibliographical note

Work performed by Solar Energy Research Institute, Golden, Colorado; North Carolina State University, Raleigh, North Carolina; Science University of Tokyo, Tokyo, Japan; Universidad de Los Andes, Merida, Venezuela; University of Groningen, Groningen, The Netherlands; Brooklyn College of CUNY, Brooklyn, New York

NLR Publication Number

ACNR/CP-212-6674

Keywords

CuInS
CuInSe
materials characterization
Photoelectrochemistry
semiconductor/liquid electrolyte
solar cell

Access to Document

10.1016/0146-3535(84)90043-1

Cite this

Cahen, D., Dagen, G., Hodes, G., Mirovsky, Y., Chen, Y. W., Folmer, J. C. W., Ireland, P. J., Noufi, R., Turner, J. A., Bachmann, K. J., Endo, S., Rincon, C., Sawatzky, G. A., & Tomkiewicz, M. (1984). n-Cu-In-Chalcogenide-Based Photoelectrochemical Cells. 263-270. Paper presented at Sixth International Conference on Ternary and Multinary Compounds, Caracas, Venezuela. https://doi.org/10.1016/0146-3535(84)90043-1

@conference{5692544ab3e2464d88241ea8eba70eac,

title = "n-Cu-In-Chalcogenide-Based Photoelectrochemical Cells",

abstract = "n-CuInSe2, n-CuInS2 and n-CuIn5S8 were used as photoanodes in electrochemical photovoltaic solar cells, using aqueous polysulfide electrolyte. CuIn5S8 was found to be less stable than CuInS2. Because of kinetic limitations of polysulfide-based systems, the CuInSe2/aqueous polyiodide cell was studied and optimized to yield stable, near 12\% AM1 conversion efficiency. The strategy used to achieve this is described. (Photo)electrochemical methods were used to characterize the semiconductor materials and a photoelectrochemical test was developed to gauge the photovoltaic activity of p-CuInSe2 layers used in solid state cells. Solid-state chemical studies on the (Cu2X)2-(In2X3)(X=S,Se) system, and the use of photoelectrochemistry in them, are briefly described.",

keywords = "CuInS, CuInSe, materials characterization, Photoelectrochemistry, semiconductor/liquid electrolyte, solar cell",

author = "David Cahen and G. Dagen and G. Hodes and Y. Mirovsky and Chen, \{Y. W.\} and Folmer, \{J. C.W.\} and Ireland, \{P. J.\} and R. Noufi and Turner, \{J. A.\} and Bachmann, \{K. J.\} and S. Endo and C. Rincon and Sawatzky, \{G. A.\} and M. Tomkiewicz",

note = "Work performed by Solar Energy Research Institute, Golden, Colorado; North Carolina State University, Raleigh, North Carolina; Science University of Tokyo, Tokyo, Japan; Universidad de Los Andes, Merida, Venezuela; University of Groningen, Groningen, The Netherlands; Brooklyn College of CUNY, Brooklyn, New York; Sixth International Conference on Ternary and Multinary Compounds ; Conference date: 15-08-1984 Through 17-08-1984",

year = "1984",

doi = "10.1016/0146-3535(84)90043-1",

language = "American English",

pages = "263--270",

}

Cahen, D, Dagen, G, Hodes, G, Mirovsky, Y, Chen, YW, Folmer, JCW, Ireland, PJ, Noufi, R, Turner, JA, Bachmann, KJ, Endo, S, Rincon, C, Sawatzky, GA & Tomkiewicz, M 1984, 'n-Cu-In-Chalcogenide-Based Photoelectrochemical Cells', Paper presented at Sixth International Conference on Ternary and Multinary Compounds, Caracas, Venezuela, 15/08/84 - 17/08/84 pp. 263-270. https://doi.org/10.1016/0146-3535(84)90043-1

TY - CONF

T1 - n-Cu-In-Chalcogenide-Based Photoelectrochemical Cells

AU - Cahen, David

AU - Dagen, G.

AU - Hodes, G.

AU - Mirovsky, Y.

AU - Chen, Y. W.

AU - Folmer, J. C.W.

AU - Ireland, P. J.

AU - Noufi, R.

AU - Turner, J. A.

AU - Bachmann, K. J.

AU - Endo, S.

AU - Rincon, C.

AU - Sawatzky, G. A.

AU - Tomkiewicz, M.

N1 - Work performed by Solar Energy Research Institute, Golden, Colorado; North Carolina State University, Raleigh, North Carolina; Science University of Tokyo, Tokyo, Japan; Universidad de Los Andes, Merida, Venezuela; University of Groningen, Groningen, The Netherlands; Brooklyn College of CUNY, Brooklyn, New York

PY - 1984

Y1 - 1984

N2 - n-CuInSe2, n-CuInS2 and n-CuIn5S8 were used as photoanodes in electrochemical photovoltaic solar cells, using aqueous polysulfide electrolyte. CuIn5S8 was found to be less stable than CuInS2. Because of kinetic limitations of polysulfide-based systems, the CuInSe2/aqueous polyiodide cell was studied and optimized to yield stable, near 12% AM1 conversion efficiency. The strategy used to achieve this is described. (Photo)electrochemical methods were used to characterize the semiconductor materials and a photoelectrochemical test was developed to gauge the photovoltaic activity of p-CuInSe2 layers used in solid state cells. Solid-state chemical studies on the (Cu2X)2-(In2X3)(X=S,Se) system, and the use of photoelectrochemistry in them, are briefly described.

AB - n-CuInSe2, n-CuInS2 and n-CuIn5S8 were used as photoanodes in electrochemical photovoltaic solar cells, using aqueous polysulfide electrolyte. CuIn5S8 was found to be less stable than CuInS2. Because of kinetic limitations of polysulfide-based systems, the CuInSe2/aqueous polyiodide cell was studied and optimized to yield stable, near 12% AM1 conversion efficiency. The strategy used to achieve this is described. (Photo)electrochemical methods were used to characterize the semiconductor materials and a photoelectrochemical test was developed to gauge the photovoltaic activity of p-CuInSe2 layers used in solid state cells. Solid-state chemical studies on the (Cu2X)2-(In2X3)(X=S,Se) system, and the use of photoelectrochemistry in them, are briefly described.

KW - CuInS

KW - CuInSe

KW - materials characterization

KW - Photoelectrochemistry

KW - semiconductor/liquid electrolyte

KW - solar cell

UR - https://www.scopus.com/pages/publications/0021559102

U2 - 10.1016/0146-3535(84)90043-1

DO - 10.1016/0146-3535(84)90043-1

M3 - Paper

AN - SCOPUS:0021559102

SP - 263

EP - 270

T2 - Sixth International Conference on Ternary and Multinary Compounds

Y2 - 15 August 1984 through 17 August 1984

ER -

n-Cu-In-Chalcogenide-Based Photoelectrochemical Cells

Abstract

Conference

Bibliographical note

NLR Publication Number

Keywords

Access to Document

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