Na Impurity Chemistry in Photovoltaic CIGS Thin-Films: An Investigation with Photo- and Auger Electron Spectroscopies

    Research output: Contribution to conferencePaper

    Abstract

    The incorporation of Na into Cu(In1-xGax)Se2 thin-films is known to lead to an improvement in device performance. The authors use X-ray photoelectron and Auger election spectroscopies to determine the chemical nature of Na in Cu(In1-xGax)Se2 thin-films. The Na concentration is determined to be approx. 0.1 atomic percent in the bulk of Cu(In1-xGax)Se2 thin-films. The Na is chemically bonded to Se.The authors propose a model invoking the replacement of column III elements by Na during growth of Cu(In1-xGax)Se2 thin-films. These NaIn and NaGa defects act as acceptor states to increase the p-type conductivity of Cu(In1-xGax)Se2 thin-films.
    Original languageAmerican English
    Pages179-184
    Number of pages6
    StatePublished - 1998
    EventThin-Film Structures for Photovoltaics: Materials Research Society Symposium - Boston, Massachusetts
    Duration: 2 Dec 19975 Dec 1997

    Conference

    ConferenceThin-Film Structures for Photovoltaics: Materials Research Society Symposium
    CityBoston, Massachusetts
    Period2/12/975/12/97

    NREL Publication Number

    • NREL/CP-530-23901

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