TY - JOUR
T1 - Photoelectrochemical Characterization of Several Semiconducting Compounds of Palladium with Sulfur and/or Phosphorus
AU - Folmer, J. C.W.
AU - Turner, J. A.
AU - Parkinson, B. A.
PY - 1987
Y1 - 1987
N2 - Semiconducting compounds of palladium with sulfur and/or phosphorus were prepared as crystals and their semiconducting and photoelectrochemical properties studied. The compounds include PdS, PdPS, Pd3(PS4)2, and PdP2 and crystal growth was accomplished by chemical vapor transport with halogens and Bridgeman methods. Photoelectrochemical techniques were used to measure bandgap, transition type, doping level, majority carrier type, flatband potential, quantum yield for electron flow, and stability in a photoelectrochemical cell. The previously undetermined bandgap of PdP2 is reported (1.08 eV, indirect).
AB - Semiconducting compounds of palladium with sulfur and/or phosphorus were prepared as crystals and their semiconducting and photoelectrochemical properties studied. The compounds include PdS, PdPS, Pd3(PS4)2, and PdP2 and crystal growth was accomplished by chemical vapor transport with halogens and Bridgeman methods. Photoelectrochemical techniques were used to measure bandgap, transition type, doping level, majority carrier type, flatband potential, quantum yield for electron flow, and stability in a photoelectrochemical cell. The previously undetermined bandgap of PdP2 is reported (1.08 eV, indirect).
UR - http://www.scopus.com/inward/record.url?scp=0023344169&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(87)90281-7
DO - 10.1016/0022-4596(87)90281-7
M3 - Article
AN - SCOPUS:0023344169
SN - 0022-4596
VL - 68
SP - 28
EP - 37
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 1
ER -