Polymer Degradation on Reflecting Metal Films: Fourier Transform Infrared (FTIR) Reflection-Absorbance Studies

    Research output: NRELTechnical Report

    Abstract

    The technique of Fourier transform infrared reflection-absorption (FTIR-RA) spectroscopy has been successfully adapted co studying bulk and interfacially activated photodegradation of several types of polymers on various metallic substrates. The technique enables qualitative and quantitative study of photochemical reaction mechanisms and races. A Controlled Environmental Exposure Chamber (CEEC),which permits collection of IR-RA spectra of the polymer/metal samples during their exposure to controlled spectral distributions of UV, temperatures, and gas mixtures, was built into the sample compartment of a Nicolet 7199 FTIR spectrophotometer. Surface analysis, gel permeation chromatography (GPC), UV spectroscopy, and UV spectroradiometry were used to complement the FTIR-RA results.
    Original languageAmerican English
    Number of pages9
    StatePublished - 1983

    NREL Publication Number

    • NREL/TP-255-2054

    Keywords

    • fourier transform infrared spectroscopy (FTIR)
    • fourier transform infrared spectroscopy (FTIR)
    • polymer degradation

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