Abstract
Current methods for separations of critical rare earth elements (REEs) require multi-step, waste-generating procedures that lack the ability to selectively separate similarly sized ions, despite such an onerous process. REEs possess unique optoelectronic properties that are often exploited for photomagnetic or photoluminescent applications but could be harnessed to drive element selective separations. Recent work exploring photochemical reactions of REE complexes points to promise for investigating alternative separations using photoactive molecules and macromolecular frameworks, highlighting a possible pathway towards realizing practical REE separations to increase the sustainability and longevity of mining and recycling these elements.
Original language | American English |
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Pages (from-to) | 432-446 |
Number of pages | 15 |
Journal | Trends in Chemistry |
Volume | 6 |
Issue number | 8 |
DOIs | |
State | Published - 2024 |
NREL Publication Number
- NREL/JA-5900-89891
Keywords
- critical materials
- photochemistry
- photoswitch
- rare earth
- separations