Raman Studies of Nanocrystalline CdS:O Film

Research output: Contribution to conferencePaper


Oxygenated nanocrystalline CdS films show improved solar cell performance, but the physics and mechanism underlying this are not yet clearly understood. Raman study provides complementary information to the understanding obtained from other experimental investigations. A comprehensive analysis of the existing experimental data (including x-ray diffraction, transmission, transmission electronmicroscopy, and Raman) has led to the following conclusions: (1) The O-incorporation forms CdS1-xOx alloy nano-particles. (2) The observed evolution of the electronic structure is the result of the interplay between the alloy and quantum confinement effect. (3) The blue-shift of the LO phonon Raman peak is primarily due to the alloying effect. (4) Some oxygen atoms have taken the interstitialsites.
Original languageAmerican English
Number of pages5
StatePublished - 2005
Event2004 DOE Solar Energy Technologies Program Review Meeting - Denver, Colorado
Duration: 25 Oct 200428 Oct 2004


Conference2004 DOE Solar Energy Technologies Program Review Meeting
CityDenver, Colorado

Bibliographical note

Presented at the 2004 DOE Solar Energy Technologies Program Review Meeting, 25-28 October 2004, Denver, Colorado. Also included in the proceedings available on CD-ROM (DOE/GO-102005-2067; NREL/CD-520-37140)

NREL Publication Number

  • NREL/CP-590-37026


  • electronic and optical properties
  • oxygenated nanocrystalline
  • PV
  • raman studies
  • solar cell performance
  • transmission electron microscopy (TEM)
  • x-ray diffraction (XRD)


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