Abstract
Front/back poly-Si/SiO2 contact devices suffer from low short-circuit current density, Jsc, due to parasitic optical absorption in the front poly-Si layer. Thin poly-Si (~20 nm) allows for high Jsc but is not compatible with screen-printed fire-through contacts. We therefore study the effects of post-deposition etching of a thick poly-Si (200 nm) front layer by reactive ion etching (RIE) using the metal grid lines as a self-aligned mask. We show that passivation is maintained in the device during RIE and that Jsc is increased by a gain in the blue quantum efficiency response. However, our specific etching parameters cause non-uniform etching of the poly-Si leading to premature loss of passivation without optimal gain in Jsc. Etched, unpassivated layers can be re-passivated with a H-containing dielectric layer leading to a gain in Jsc, open circuit voltage,Voc, Fill-Factor, FF, and efficiency.
Original language | American English |
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Article number | Article No. 110621 |
Number of pages | 8 |
Journal | Solar Energy Materials and Solar Cells |
Volume | 217 |
DOIs | |
State | Published - Nov 2020 |
Bibliographical note
Publisher Copyright:© 2020 Elsevier B.V.
NREL Publication Number
- NREL/JA-5900-74988
Keywords
- Ohmic contacts
- Passivation
- Photovoltaic cells
- Poly-Si contacts
- Reactive ion etching
- Silicon devices