Reducing Delamination of an Electron-Transporting Polymer from a Metal Oxide for Electrochemical Applications

Aiswarya Abhisek Mohapatra; Waleed Yual; Yadong Zhang; Anton Samoylov; Jonathan Thurston; Casey Davis; Declan McCarthy; Adam Printz; Michael Toney; Erin Ratcliff; Neal Armstrong; Ann Greenaway; Stephen Barlow; Seth Marder

doi:10.1039/D3CC05391A

Reducing Delamination of an Electron-Transporting Polymer from a Metal Oxide for Electrochemical Applications

Aiswarya Abhisek Mohapatra, Waleed Yual, Yadong Zhang, Anton Samoylov, Jonathan Thurston, Casey Davis, Declan McCarthy, Adam Printz, Michael Toney, Erin Ratcliff, Neal Armstrong, Ann Greenaway, Stephen Barlow, Seth Marder

Materials Science

Research output: Contribution to journal › Article › peer-review

Abstract

Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

Original language	American English
Pages (from-to)	988-991
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	8
DOIs	https://doi.org/10.1039/D3CC05391A
State	Published - 2024

NREL Publication Number

NREL/JA-5K00-87974

Keywords

electrochemistry
photoelectrochemical
polymer

Access to Document

10.1039/D3CC05391A

Cite this

Mohapatra, A. A., Yual, W., Zhang, Y., Samoylov, A., Thurston, J., Davis, C., McCarthy, D., Printz, A., Toney, M., Ratcliff, E., Armstrong, N., Greenaway, A., Barlow, S., & Marder, S. (2024). Reducing Delamination of an Electron-Transporting Polymer from a Metal Oxide for Electrochemical Applications. Chemical Communications, 60(8), 988-991. https://doi.org/10.1039/D3CC05391A

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abstract = "Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.",

keywords = "electrochemistry, photoelectrochemical, polymer",

author = "Mohapatra, {Aiswarya Abhisek} and Waleed Yual and Yadong Zhang and Anton Samoylov and Jonathan Thurston and Casey Davis and Declan McCarthy and Adam Printz and Michael Toney and Erin Ratcliff and Neal Armstrong and Ann Greenaway and Stephen Barlow and Seth Marder",

year = "2024",

doi = "10.1039/D3CC05391A",

language = "American English",

volume = "60",

pages = "988--991",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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Mohapatra, AA, Yual, W, Zhang, Y, Samoylov, A, Thurston, J, Davis, C, McCarthy, D, Printz, A, Toney, M, Ratcliff, E, Armstrong, N, Greenaway, A, Barlow, S & Marder, S 2024, 'Reducing Delamination of an Electron-Transporting Polymer from a Metal Oxide for Electrochemical Applications', Chemical Communications, vol. 60, no. 8, pp. 988-991. https://doi.org/10.1039/D3CC05391A

TY - JOUR

T1 - Reducing Delamination of an Electron-Transporting Polymer from a Metal Oxide for Electrochemical Applications

AU - Mohapatra, Aiswarya Abhisek

AU - Yual, Waleed

AU - Zhang, Yadong

AU - Samoylov, Anton

AU - Thurston, Jonathan

AU - Davis, Casey

AU - McCarthy, Declan

AU - Printz, Adam

AU - Toney, Michael

AU - Ratcliff, Erin

AU - Armstrong, Neal

AU - Greenaway, Ann

AU - Barlow, Stephen

AU - Marder, Seth

PY - 2024

Y1 - 2024

N2 - Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

AB - Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

KW - electrochemistry

KW - photoelectrochemical

KW - polymer

U2 - 10.1039/D3CC05391A

DO - 10.1039/D3CC05391A

M3 - Article

SN - 1359-7345

VL - 60

SP - 988

EP - 991

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Reducing Delamination of an Electron-Transporting Polymer from a Metal Oxide for Electrochemical Applications

Abstract

NREL Publication Number

Keywords

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