Regulating Surface Potential Maximizes Voltage in All-Perovskite Tandems

Hao Chen, Aidan Maxwell, Chongwen Li, Sam Teale, Bin Chen, Tong Zhu, Esma Ugur, George Harrison, Luke Grater, Junke Wang, Zaiwei Wang, Lewei Zeng, So Min Park, Lei Chen, Peter Serles, Rasha Awni, Biwas Subedi, Xiaopeng Zheng, Chuanxiao Xiao, Nikolas PodrazaTobin Filleter, Cheng Liu, Yi Yang, Joseph Luther, Stefaan De Wolf, Mercouri Kanatzidis, Yanfa Yan, Edward Sargent

Research output: Contribution to journalArticlepeer-review

195 Scopus Citations

Abstract

The open-circuit voltage (VOC) deficit in perovskite solar cells is greater in wide-bandgap (over 1.7 eV) cells than in perovskites of roughly 1.5 eV (refs. 1,2). Quasi-Fermi-level-splitting measurements show VOC-limiting recombination at the electron-transport-layer contact3–5. This, we find, stems from inhomogeneous surface potential and poor perovskite–electron transport layer energetic alignment. Common monoammonium surface treatments fail to address this; as an alternative, we introduce diammonium molecules to modify perovskite surface states and achieve a more uniform spatial distribution of surface potential. Using 1,3-propane diammonium, quasi-Fermi-level splitting increases by 90 meV, enabling 1.79 eV perovskite solar cells with a certified 1.33 V VOC and over 19% power conversion efficiency (PCE). Incorporating this layer into a monolithic all-perovskite tandem, we report a record VOC of 2.19 V (89% of the detailed balance VOC limit) and over 27% PCE (26.3% certified quasi-steady state). These tandems retained more than 86% of their initial PCE after 500 h of operation.

Original languageAmerican English
Pages (from-to)676-681
Number of pages6
JournalNature
Volume613
Issue number7945
DOIs
StatePublished - 2023

Bibliographical note

Publisher Copyright:
© 2022, The Author(s), under exclusive licence to Springer Nature Limited.

NREL Publication Number

  • NREL/JA-5900-83296

Keywords

  • all perovskite tandem
  • electronic properties
  • perovskite solar cell
  • photonic devices

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