Spatially-Resolved Studies of Grain-Boundary Effects in Polycrystalline Solar Cells Using Micro-Photoluminescence and Near-Field Microscopy

Research output: Contribution to conferencePaper

Abstract

Photoluminescence and photocurrent spectroscopies combined with diffraction-limited and sub- diffraction-limited spatial resolution are achieved via micro-photoluminescence (m-PL) and near-field microscopy (NSOM). These methods are used to examine the photo-response of individual grain boundaries in thin-film, polycrystalline solar cells at room and cryogenic temperatures. A systematic m-PL studyof the effect of CdCl2-treatment on recombination in CdTe/CdS solar cell structures of varying thickness directly reveals the grain-boundary and surface passivation action of this important post-growth processing step. We achieve 50nm (l/10) spatial resolution in near-field Optical Beam Induced Current imaging (n-OBIC) of polycrystalline silicon solar cells using NSOM, at varying stages ofsilicon nitride grain-boundary passivation, and measure lateral variations in photo-response of CdTe/CdS solar cells with subwavelength spatial resolution.
Original languageAmerican English
Number of pages5
StatePublished - 2005
Event2004 DOE Solar Energy Technologies Program Review Meeting - Denver, Colorado
Duration: 25 Oct 200428 Oct 2004

Conference

Conference2004 DOE Solar Energy Technologies Program Review Meeting
CityDenver, Colorado
Period25/10/0428/10/04

Bibliographical note

Presented at the 2004 DOE Solar Energy Technologies Program Review Meeting, 25-28 October 2004, Denver, Colorado. Also included in the proceedings available on CD-ROM (DOE/GO-102005-2067; NREL/CD-520-37140)

NREL Publication Number

  • NREL/CP-590-37037

Keywords

  • diffraction-limited
  • grain boundary (GBS)
  • micro-photoluminescence (m-PL)
  • near-field scanning optical microscopy (NSOM)
  • photocurrent
  • photoluminescence
  • polycrystalline silicon
  • PV
  • solar cells
  • spatially resolution
  • spectroscopic
  • sub- diffraction-limited

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