Stable Cycling of Thin-Film Vanadium Oxide Electrodes between 4 and 0 V in Lithium Batteries

Ping Liu; Se Hee Lee; C. Edwin Tracy; John A. Turner

doi:10.1016/S0378-7753(03)00164-2

Stable Cycling of Thin-Film Vanadium Oxide Electrodes between 4 and 0 V in Lithium Batteries

Ping Liu, Se Hee Lee, C. Edwin Tracy, John A. Turner

Chemistry and Nanoscience

National Renewable Energy Laboratory

Research output: Contribution to journal › Article › peer-review

13 Scopus Citations

Abstract

Vanadium oxide prepared by plasma-enhanced chemical vapor deposition was cycled in different voltage ranges in a lithium battery. Electrochemical cycling results show a surprisingly low irreversibility during the first discharge and good stability for close to 1000 cycles between 4 and 0 V. Raman spectroscopy results indicate that a major structural transformation takes place when the films are cycled down to 1.8 V, after which the structural features remain intact even after cycling to 0 V. Degradation of the electrode only occurs after extended cycling.

Original language	American English
Pages (from-to)	305-309
Number of pages	5
Journal	Journal of Power Sources
Volume	119-121
DOIs	https://doi.org/10.1016/S0378-7753(03)00164-2 https://doi.org/10.1016/S0378-7753(03)00164-2
State	Published - 2003
Event	Selected Papers Presented at the 11th IMLB - Monterey, CA, United States Duration: 22 Jun 2002 → 28 Jun 2002

NREL Publication Number

NREL/JA-590-34997

Keywords

Anode material
Cycling stability
Lithium insertion
Raman spectra
Vanadium oxide

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title = "Stable Cycling of Thin-Film Vanadium Oxide Electrodes between 4 and 0 V in Lithium Batteries",

abstract = "Vanadium oxide prepared by plasma-enhanced chemical vapor deposition was cycled in different voltage ranges in a lithium battery. Electrochemical cycling results show a surprisingly low irreversibility during the first discharge and good stability for close to 1000 cycles between 4 and 0 V. Raman spectroscopy results indicate that a major structural transformation takes place when the films are cycled down to 1.8 V, after which the structural features remain intact even after cycling to 0 V. Degradation of the electrode only occurs after extended cycling.",

keywords = "Anode material, Cycling stability, Lithium insertion, Raman spectra, Vanadium oxide",

author = "Ping Liu and Lee, {Se Hee} and Tracy, {C. Edwin} and Turner, {John A.}",

year = "2003",

doi = "10.1016/S0378-7753(03)00164-2",

language = "American English",

volume = "119-121",

pages = "305--309",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier B.V.",

note = "Selected Papers Presented at the 11th IMLB ; Conference date: 22-06-2002 Through 28-06-2002",

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TY - JOUR

T1 - Stable Cycling of Thin-Film Vanadium Oxide Electrodes between 4 and 0 V in Lithium Batteries

AU - Liu, Ping

AU - Lee, Se Hee

AU - Tracy, C. Edwin

AU - Turner, John A.

PY - 2003

Y1 - 2003

N2 - Vanadium oxide prepared by plasma-enhanced chemical vapor deposition was cycled in different voltage ranges in a lithium battery. Electrochemical cycling results show a surprisingly low irreversibility during the first discharge and good stability for close to 1000 cycles between 4 and 0 V. Raman spectroscopy results indicate that a major structural transformation takes place when the films are cycled down to 1.8 V, after which the structural features remain intact even after cycling to 0 V. Degradation of the electrode only occurs after extended cycling.

AB - Vanadium oxide prepared by plasma-enhanced chemical vapor deposition was cycled in different voltage ranges in a lithium battery. Electrochemical cycling results show a surprisingly low irreversibility during the first discharge and good stability for close to 1000 cycles between 4 and 0 V. Raman spectroscopy results indicate that a major structural transformation takes place when the films are cycled down to 1.8 V, after which the structural features remain intact even after cycling to 0 V. Degradation of the electrode only occurs after extended cycling.

KW - Anode material

KW - Cycling stability

KW - Lithium insertion

KW - Raman spectra

KW - Vanadium oxide

UR - http://www.scopus.com/inward/record.url?scp=0038686863&partnerID=8YFLogxK

U2 - 10.1016/S0378-7753(03)00164-2

DO - 10.1016/S0378-7753(03)00164-2

M3 - Article

AN - SCOPUS:0038686863

SN - 0378-7753

VL - 119-121

SP - 305

EP - 309

JO - Journal of Power Sources

JF - Journal of Power Sources

T2 - Selected Papers Presented at the 11th IMLB

Y2 - 22 June 2002 through 28 June 2002

ER -

Stable Cycling of Thin-Film Vanadium Oxide Electrodes between 4 and 0 V in Lithium Batteries

Abstract

NREL Publication Number

Keywords

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