Strongly Enhanced Photovoltaic Performance and Defect Physics of Air-Stable Bismuth Oxyiodide (BiOI)

Vladan Stevanovic, Robert Hoye, Lana Lee, Rachel Kurchin, Tahmida Huq, Kelvin Zhang, Melany Sponseller, Lea Nienhaus, Riley Brandt, Joel Jean, James Polizzotti, Ahmed Kursumovic, Moungi Bawendi, Vladimir Bulovic, Tonio Buonassisi, Judith MacManus-Driscoll

Research output: Contribution to journalArticlepeer-review

141 Scopus Citations

Abstract

Bismuth-based compounds have recently gained increasing attention as potentially nontoxic and defect-tolerant solar absorbers. However, many of the new materials recently investigated show limited photovoltaic performance. Herein, one such compound is explored in detail through theory and experiment: bismuth oxyiodide (BiOI). BiOI thin films are grown by chemical vapor transport and found to maintain the same tetragonal phase in ambient air for at least 197 d. The computations suggest BiOI to be tolerant to antisite and vacancy defects. All-inorganic solar cells (ITO|NiOx|BiOI|ZnO|Al) with negligible hysteresis and up to 80% external quantum efficiency under select monochromatic excitation are demonstrated. The short-circuit current densities and power conversion efficiencies under AM 1.5G illumination are nearly double those of previously reported BiOI solar cells, as well as other bismuth halide and chalcohalide photovoltaics recently explored by many groups. Through a detailed loss analysis using optical characterization, photoemission spectroscopy, and device modeling, direction for future improvements in efficiency is provided. This work demonstrates that BiOI, previously considered to be a poor photocatalyst, is promising for photovoltaics.
Original languageAmerican English
Number of pages10
JournalAdvanced Materials
Volume29
Issue number36
DOIs
StatePublished - 2017

NREL Publication Number

  • NREL/JA-5K00-68975

Keywords

  • air-stability
  • bismuth oxyiodide
  • defect-tolerance
  • ns2 compounds
  • photovoltaics

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