Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4

V. Cloet; A. Raw; K. R. Poeppelmeier; G. Trimarchi; H. Peng; J. Im; A. J. Freeman; N. H. Perry; T. O. Mason; A. Zakutayev; P. F. Ndione; D. S. Ginley; J. D. Perkins

doi:10.1021/cm301119c

Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4

V. Cloet, A. Raw, K. R. Poeppelmeier, G. Trimarchi, H. Peng, J. Im, A. J. Freeman, N. H. Perry, T. O. Mason, A. Zakutayev, P. F. Ndione, D. S. Ginley, J. D. Perkins

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Abstract

The structures of α- and β-Ag ₃VO ₄ were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag ₃VO ₄ reversibly transitioned between α-Ag ₃VO ₄ and β-Ag ₃VO ₄. The optical and electrical properties of polycrystalline α-Ag ₃VO ₄ were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag ₃VO ₄, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag ₃VO ₄ were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag ₃VO ₄ thin films were compared with the bulk properties.

Original language	American English
Pages (from-to)	3346-3354
Number of pages	9
Journal	Chemistry of Materials
Volume	24
Issue number	17
DOIs	https://doi.org/10.1021/cm301119c https://doi.org/10.1021/cm301119c
State	Published - 11 Sep 2012

NREL Publication Number

NREL/JA-5200-56826

Keywords

α-Ag VO
β-Ag VO
electrical conductivity
single crystal
thin film

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Cloet, V., Raw, A., Poeppelmeier, K. R., Trimarchi, G., Peng, H., Im, J., Freeman, A. J., Perry, N. H., Mason, T. O., Zakutayev, A., Ndione, P. F., Ginley, D. S., & Perkins, J. D. (2012). Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4. Chemistry of Materials, 24(17), 3346-3354. https://doi.org/10.1021/cm301119c, https://doi.org/10.1021/cm301119c

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title = "Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4",

abstract = "The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.",

keywords = "α-Ag VO, β-Ag VO, electrical conductivity, single crystal, thin film",

author = "V. Cloet and A. Raw and Poeppelmeier, \{K. R.\} and G. Trimarchi and H. Peng and J. Im and Freeman, \{A. J.\} and Perry, \{N. H.\} and Mason, \{T. O.\} and A. Zakutayev and Ndione, \{P. F.\} and Ginley, \{D. S.\} and Perkins, \{J. D.\}",

year = "2012",

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doi = "10.1021/cm301119c",

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AU - Cloet, V.

AU - Raw, A.

AU - Poeppelmeier, K. R.

AU - Trimarchi, G.

AU - Peng, H.

AU - Im, J.

AU - Freeman, A. J.

AU - Perry, N. H.

AU - Mason, T. O.

AU - Zakutayev, A.

AU - Ndione, P. F.

AU - Ginley, D. S.

AU - Perkins, J. D.

PY - 2012/9/11

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N2 - The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

AB - The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

KW - α-Ag VO

KW - β-Ag VO

KW - electrical conductivity

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KW - thin film

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DO - 10.1021/cm301119c

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AN - SCOPUS:84866064302

SN - 0897-4756

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JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 17

ER -

Structural, Optical, and Transport Properties of ..alpha..- and ..beta...-Ag3VO4

Abstract

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Keywords

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