Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries

J. M. McGraw; J. D. Perkins; J. G. Zhang; P. A. Parilla; T. F. Ciszek; M. L. Fu; D. M. Trickett; J. A. Turner; D. S. Ginley

Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries

J. M. McGraw
, J. D. Perkins
, J. G. Zhang
, P. A. Parilla
, T. F. Ciszek
, M. L. Fu
, D. M. Trickett
, J. A. Turner
, D. S. Ginley

Research output: Contribution to conference › Paper › peer-review

4 Scopus Citations

Abstract

We report on investigations of V₂O₅ thin film cathodes prepared by pulsed laser deposition and the phase transformations which occur during electrochemical cycling. Our experimental results on PLD-grown, textured V₂O₅ crystalline films concur with reports in the literature that there is a voltage threshold above which, cycling appears to be completely reversible and below which, cycling appears to be irreversible. Crystalline films discharged beyond the threshold to 2.0 V vs. Li exhibited an immediate and continuous fade in capacity as well as a approximately 90% decrease in XRD peak intensity and a similar decrease in Raman signal intensity in as few as 10 cycles. We have made ω-phase material by both electrochemically discharging virgin, crystalline V₂O₅ and by further discharging previously cycled films which showed irreversible structural changes.

Original language	American English
Pages	373-378
Number of pages	6
State	Published - 1998
Event	Materials for Electrochemical Energy Storage and Conversion II Batteries, Capacitors and Fuel Cells: Materials Research Society Symposium - Boston, Massachusetts Duration: 1 Dec 1997 → 5 Dec 1997

Conference

Conference	Materials for Electrochemical Energy Storage and Conversion II Batteries, Capacitors and Fuel Cells: Materials Research Society Symposium
City	Boston, Massachusetts
Period	1/12/97 → 5/12/97

NLR Publication Number

NREL/CP-590-25596

Cite this

McGraw, J. M., Perkins, J. D., Zhang, J. G., Parilla, P. A., Ciszek, T. F., Fu, M. L., Trickett, D. M., Turner, J. A., & Ginley, D. S. (1998). Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries. 373-378. Paper presented at Materials for Electrochemical Energy Storage and Conversion II Batteries, Capacitors and Fuel Cells: Materials Research Society Symposium, Boston, Massachusetts.

@conference{9a13aa6b567e44439a07cf84c7f0c2f0,

title = "Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries",

abstract = "We report on investigations of V2O5 thin film cathodes prepared by pulsed laser deposition and the phase transformations which occur during electrochemical cycling. Our experimental results on PLD-grown, textured V2O5 crystalline films concur with reports in the literature that there is a voltage threshold above which, cycling appears to be completely reversible and below which, cycling appears to be irreversible. Crystalline films discharged beyond the threshold to 2.0 V vs. Li exhibited an immediate and continuous fade in capacity as well as a approximately 90\% decrease in XRD peak intensity and a similar decrease in Raman signal intensity in as few as 10 cycles. We have made ω-phase material by both electrochemically discharging virgin, crystalline V2O5 and by further discharging previously cycled films which showed irreversible structural changes.",

author = "McGraw, \{J. M.\} and Perkins, \{J. D.\} and Zhang, \{J. G.\} and Parilla, \{P. A.\} and Ciszek, \{T. F.\} and Fu, \{M. L.\} and Trickett, \{D. M.\} and Turner, \{J. A.\} and Ginley, \{D. S.\}",

year = "1998",

language = "American English",

pages = "373--378",

note = "Materials for Electrochemical Energy Storage and Conversion II Batteries, Capacitors and Fuel Cells: Materials Research Society Symposium ; Conference date: 01-12-1997 Through 05-12-1997",

}

McGraw, JM, Perkins, JD, Zhang, JG, Parilla, PA, Ciszek, TF, Fu, ML, Trickett, DM, Turner, JA & Ginley, DS 1998, 'Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries', Paper presented at Materials for Electrochemical Energy Storage and Conversion II Batteries, Capacitors and Fuel Cells: Materials Research Society Symposium, Boston, Massachusetts, 1/12/97 - 5/12/97 pp. 373-378.

Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries. / McGraw, J. M.; Perkins, J. D.; Zhang, J. G. et al.
1998. 373-378 Paper presented at Materials for Electrochemical Energy Storage and Conversion II Batteries, Capacitors and Fuel Cells: Materials Research Society Symposium, Boston, Massachusetts.

Research output: Contribution to conference › Paper › peer-review

TY - CONF

T1 - Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries

AU - McGraw, J. M.

AU - Perkins, J. D.

AU - Zhang, J. G.

AU - Parilla, P. A.

AU - Ciszek, T. F.

AU - Fu, M. L.

AU - Trickett, D. M.

AU - Turner, J. A.

AU - Ginley, D. S.

PY - 1998

Y1 - 1998

N2 - We report on investigations of V2O5 thin film cathodes prepared by pulsed laser deposition and the phase transformations which occur during electrochemical cycling. Our experimental results on PLD-grown, textured V2O5 crystalline films concur with reports in the literature that there is a voltage threshold above which, cycling appears to be completely reversible and below which, cycling appears to be irreversible. Crystalline films discharged beyond the threshold to 2.0 V vs. Li exhibited an immediate and continuous fade in capacity as well as a approximately 90% decrease in XRD peak intensity and a similar decrease in Raman signal intensity in as few as 10 cycles. We have made ω-phase material by both electrochemically discharging virgin, crystalline V2O5 and by further discharging previously cycled films which showed irreversible structural changes.

AB - We report on investigations of V2O5 thin film cathodes prepared by pulsed laser deposition and the phase transformations which occur during electrochemical cycling. Our experimental results on PLD-grown, textured V2O5 crystalline films concur with reports in the literature that there is a voltage threshold above which, cycling appears to be completely reversible and below which, cycling appears to be irreversible. Crystalline films discharged beyond the threshold to 2.0 V vs. Li exhibited an immediate and continuous fade in capacity as well as a approximately 90% decrease in XRD peak intensity and a similar decrease in Raman signal intensity in as few as 10 cycles. We have made ω-phase material by both electrochemically discharging virgin, crystalline V2O5 and by further discharging previously cycled films which showed irreversible structural changes.

UR - https://www.scopus.com/pages/publications/0031635161

M3 - Paper

AN - SCOPUS:0031635161

SP - 373

EP - 378

T2 - Materials for Electrochemical Energy Storage and Conversion II Batteries, Capacitors and Fuel Cells: Materials Research Society Symposium

Y2 - 1 December 1997 through 5 December 1997

ER -

Structural Phase Transformations in V2O5 Thin Film Cathode Material for Li Rechargeable Batteries

Abstract

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